f(o)= KBT Vc 1 |--ømø + (1 − 6) ln(1 − 6) + x6(1 − ø) N Π II = kBT [ф Vc N X In(1 - 6) - 6- x6² - to:²] = 1 1 + 21 6 No (2.62) (2.66) (3) Following Sec. 2.4.1, using the (mean-field) Flory-Huggin free energy of mixing for a polymer solution (Eq. (2.62)), derive Eq. (2.63) and hence the van't Hoff's law. Show that the coexistence curve is given by (2.66) and compute the critical point. (2.63)

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f(o)=
KBT
Vc
1
|--ømø + (1 − 6) ln(1 − 6) + x6(1 − ø)
N
Π II =
kBT [ф
Vc
N
X
In(1 - 6) - 6- x6²
- to:²]
=
1
1
+
21 6 No
(2.62)
(2.66)
(3) Following Sec. 2.4.1, using the (mean-field) Flory-Huggin free energy of
mixing for a polymer solution (Eq. (2.62)), derive Eq. (2.63) and hence the
van't Hoff's law. Show that the coexistence curve is given by (2.66) and compute
the critical point.
(2.63)
Transcribed Image Text:f(o)= KBT Vc 1 |--ømø + (1 − 6) ln(1 − 6) + x6(1 − ø) N Π II = kBT [ф Vc N X In(1 - 6) - 6- x6² - to:²] = 1 1 + 21 6 No (2.62) (2.66) (3) Following Sec. 2.4.1, using the (mean-field) Flory-Huggin free energy of mixing for a polymer solution (Eq. (2.62)), derive Eq. (2.63) and hence the van't Hoff's law. Show that the coexistence curve is given by (2.66) and compute the critical point. (2.63)
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