Fe3+(aq)  +  SCN–(aq)    ⇆   FeSCN2+(aq) Suppose that the solution of NaSCN was accidentally prepared using too much solid NaSCN, so that that solution had a higher [SCN-] value than expected.   How would the resulting measured Keq value differ from the true Keq value:  too large, too small, or unaffected? Explain

Chemistry: Principles and Practice
3rd Edition
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Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter15: Solutions Of Acids And Bases
Section: Chapter Questions
Problem 15.16QE
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            Fe3+(aq)  +  SCN(aq)    ⇆   FeSCN2+(aq)

Suppose that the solution of NaSCN was accidentally prepared using too much solid NaSCN, so that that solution had a higher [SCN-] value than expected.   How would the resulting measured Keq value differ from the true Keq value: 

too large, too small, or unaffected? Explain

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