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- Choose the best reagents to complete the following reaction. $ H₂O OH $ < OH A B C D E NaOH H₂O H2, Raney nickel TSOH, H₂O (CH2OH)2, TSOH DonePredict the organic products of the reaction. Show stereochemistry clearly. H X Draw the (3S,4R) product. 1) OsO4, pyridine 2) Na₂SO3 or NaHSO3 in H₂O 2 products Draw the (3R,45) product.Draw the product of the reaction shown below. Ignore inorganic byproducts. 'S ao 1 equiv H2O2 H3O+ Drawing o
- Which set of reagents will turn acetic acid into 2-bromoacetic acid? O Br2/NAOH/E1OH O Br2/PB13/heat, then water O N-bromosuccinimide (NBS), then KMNO4 O Br2/H3PO4/heat, then waterDraw the structure of the product obtained when this amine is treated with excess iodomethane and then heated with Ag₂O (Hoffman elimination). H H H CH wireframe V H C HO + labels H • Consider E/Z stereochemistry of alkenes. • Draw only the elimination product, do not the leaving group. • In cases where there is more than one answer, just draw one.Draw the product of the reaction shown below. Ignore inorganic byproducts. Na2Cr2O7 H2O, CH3CO₂H Drawing OH Q
- What is the best description of the product distribution from the reaction shown (- OTF=triflate, trifluoromethanesulfonate) Na OH,coo CH, COOHH,0 C D. DA mixture of compounds B and D OA mixture of compounds A and C OA mixture of compounds A and B OA mixture of compounds A and DSelect all major products of the following reactions. 1. H2, Pd, MeOH quinoline, Pb(OAc)2, CACO3 Me 2. Os04, NMO, H20 Me" A в E OH он Me Me Me Me Me Me Me Me OH OH Ме Me OH5) Please show the pKa numbers for the conjugate acid of each compound /ion. As best as you can, arrange the following ions in order of a) increasing leaving group, b) increasing nucleophilicity. A B C OH D E
- 4. Draw mechanisms for these reactions and explain the stereochemistry. + 1. Ph—=N0 2. LIAIH4 OH NH₂ PhWhat is the major product of the reaction below? * (1) 1 eq. Me MgCI → Major product (2) H20 HO Me Me Но OH Но OHThe formation of Br2 from NBS first involves the reaction of NBS with HBr to form an iminol intermediate and molecular bromine. The intermediate then undergoes acid-catalyzed tautomerism to form succinimide, the byproduct of the reaction. Propose a curved-arrow mechanism for the conversion of NBS into succinimide that also accounts for the formation of Br2.