Draw the product formed when phenylacetonitrile (CeH,CH2CN) is treated with each reagent. a. H3O* b. H,О, "ОН c. (1] CH3MGB3; [2] H20 d. [1] CH;CH,Li; [2] H20 e. [1] DIBAL-H; [2] H2O f. [1] LIAIH4; [2] H;O
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- Draw the products formed when p-methylaniline (p-CH3C6H4NH2) is treated with each reagent. a. HCl b. CH3COCl c. (CH3CO)2O d. excess CH3I e. (CH3)2C = O f. CH3COCl, AlCl3 g. CH3CO2H h. NaNO2, HCl i. Part (b), then CH3COCl, AlCl j. CH3CHO, NaBH3CNDraw the product formed when pentanal (CH;CH,CH2CH;CHO) is treated with each reagent. With some reagents, no reaction occurs. a. NaBH4, CH,OH b. [1] LIAIH4; (2] H20 c. H2, Pd-C d. PCC e. NazCr,07, H2SO4, H2O f. Ag,0, NH,OH g. [1) CH,MgBr; (2] H2O h. [1] CęH,Li; [2] H20 i. [1] (CH3),CuLi; (2] H2O j. [1] HC=CNa; [2] H2O k. [1] CH;C=CLi; [2] H2O I. The product in (a), then TBDMS-CI, imidazoleDraw the products formed when phenol (C6H5OH) is treated with each set of reagents.a. [1] HNO3, H2SO4; [2] Sn, HCIb. [1] (CH3CH2)2CHCOCI, AlCl3; [2] Zn(Hg), HCIc. [1] CH3CH2CI, AlCl3; [2] Br2, hvd. [1] (CH3)2CHCI, AlCl3; [2] KMnO4
- Draw the product formed when phenylacetic acid (C6H5CH2COOH) is treated with each reagent. With some reagents, no reaction occurs. a. NaHCO3 b. NaOH c. SOCl2 d. NaCl e. NH3(1equiv) f. NH3, ∆ g. CH3OH, H2SO4 h. CH3OH, −OH i. [1] NaOH; [2] CH3COCl j. CH3NH2, DCC k. [1] SOCl2; [2] CH3CH2CH2NH2 (excess) l. [1] SOCl2; [2] (CH3)2; [2] (CHBr H3CO LOCH3 A MgBr 1. CH3OH (2 equiv), H+ 2. Mg 3. 4. H30+ H3COOCH3 в ОН major organic product? НО. OH C OH D ОНDraw the organic product(s) formed when CH3CH₂CH₂OH is treated with each reagent. a. H₂SO4 d. HBr g. TsCl, pyridine b. NaH h. [1] NaH; [2] CH₂CH₂Br e. SOCI₂, pyridine f. PBr3 c. HCI + ZnCl₂ Hint: NaH deprotonates the alcohol forming an alkoxide
- taken in order to gor the product Please explain the mechanisms/stepsHO HO. OH base CI EIO- C-OEt epichlorohydrin OH NaOEt 2,6-dihydroxy- acetophenone *Na O2C. .CO2 Na* NaOH, H2O II OH Cromolyn sodium Cromolyn sodium, developed during the 1960s, has been used to prevent allergic reactions primarily affecting the lungs, as, for example, exercised- induced emphysema. It is thought to block the release of histamine, which prevents the sequence of events leading to swelling, itching, and constriction of bronchial tubes. v Cromolyn sodium is synthesized in the above series of steps. rch 31% 11:24 P 4/20/20-OH conc H3PO4 A A MCPBA CH₂Cl₂ B NaOH H₂O 8. Identify the products A,B and C.
- Determine the product formed when butanone (CH3CH,COCH3) Is treated with each reagent. If no reaction occurs, label the reaction with "no reaction". PCC H2 Pd-C HO OH NazCr,O, H,SO.H,O [1] LIAIH, [2] H,O no reaction Ag20 NH,OH NABH, CH;OH ResetDetermine the products of each carboxylic acid reaction. a. CH3-CH -C-OH + NaOH b. CH;-CH2-CH;-C-OH + CH — CH, —Сн, — онDraw the products formed when CH;CH2CH2CH2OTS is treated with each reagent. а. СH3SH b. NaOCH,CH3 c. NAOH d. KOC(CHa)3