Draw the product formed when 1-bromobutane is treated with each reagent.d. The answer in (a), then H2Oe. The answer in (b), then D,0f. The answer in (a), then CH3C=CHa. Li (2 equiv)b. Mg in (CH,CH2)2O solventc. Li (2 equiv), then Cul (0.5 equiv)

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Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Draw the products formed when D-altrose is treated with each reagent. a. (CH3)2CHOH, HCl b. NaBH4, CH3OH c. Br2, H2O d. HNO3, H2O e. [1] NH2OH; [2] (CH3CO)2O, NaOCOCH3; [3] NaOCH3 f. [1] NaCN, HCl; [2] H2, Pd-BaSO4; [3] H3O+ g. CH3I, Ag2O h. C6H5CH2NH2, mild H+
Draw the products formed when hex-1-yne is treated with each reagent. a. HCl (2 equiv) b. HBr (2 equiv) c. Cl2 (2 equiv) d.H2O + H2SO4 + HgSO4 e. [1] R2BH; [2] H2O2, HO− f. NaH g. [1] −NH2; [2] CH3CH2Br
Draw the product formed when (CH3)2CHOH is treated with each reagent. a. SOCl2, pyridine b. TsCl, pyridine c. H2SO4 d. HBr e. PBr3, then NaCN f. POCl3, pyridine
Draw the products formed when p-methylaniline (p-CH3C6H4NH2) is treated with each reagent. a. HCl b. CH3COCl c. (CH3CO)2O d. excess CH3I e. (CH3)2C = O f. CH3COCl, AlCl3 g. CH3CO2H h. NaNO2, HCl i. Part (b), then CH3COCl, AlCl j. CH3CHO, NaBH3CN
4 Identify the required reagent(s) for step 1. Select the single best answer A. Br2 , CCl4 B.Br2,H2O C. HBr D. mCPBA E.1BH3,THF;2.H2O2,NaOH F. H2O, H2SO4 Step 2: Draw the structure for compound A. Step 3: CH3CO2Na NaOCH3 CH3OH, heat H2SO4, heat t-BuOK, heat NaCN
4. Draw the products formed when 3-hexyne is treated with each reagent a. HBr(2 equivalents) b. Bra (2 equivalents) c. H₂ (2 equivalents) d. [1] 2Na [2]NH,(1)
3. What product is formed when HO(CH₂) CHO is treated with each reagent? c. Ag₂O, NH OH d. Na₂Cr₂O₂, H₂SO4, H₂O a. NaBH, CH₂OH b. PCC 400
Draw the product formed when pentanal (CH3 CH₂ CH₂ CH₂ CHO) is treated with each reagent. With some reagents, no reaction occurs. a. NaBH4, CH3OH b. [1] LiAiH4: [2] H₂O c. H₂, Pd-C d. PCC e. Na₂Cr₂O7, H₂SO4, H₂O f. Ag₂O, NH4OH g. [1] CH3 MgBr; [2] H₂O h. [1] C6H5 Li: [2] H₂O i. [1] (CH3)2 CuLi; [2] H₂O J. [1] HC=CNa; [2] H₂O k. [1] CH 3 C=CLI; [2] H₂O 1. The product in (a), then TBDMS-CI, imidazole
10. What products are formed when the following compound is treated with each reagent? If no reaction occurs, write NR. a. H₂/Pd b. K₂Cr2O7 c. Tollen's reagent d. 2 equiv. CH3OH, H+ e. 2 equiv. CH3CH₂OH, H+ f. Product of (e), then H₂O/H*
Classify each solvent as protic or aprotic. a. (CHa)2CHOH b. CH;NO2 c. CH2CI2 d. NH3 e. N(CH3)3 f. HCONH2
Draw the product formed when pentanal (CH;CH,CH2CH;CHO) is treated with each reagent. With some reagents, no reaction occurs. a. NaBH4, CH,OH b. [1] LIAIH4; (2] H20 c. H2, Pd-C d. PCC e. NazCr,07, H2SO4, H2O f. Ag,0, NH,OH g. [1) CH,MgBr; (2] H2O h. [1] CęH,Li; [2] H20 i. [1] (CH3),CuLi; (2] H2O j. [1] HC=CNa; [2] H2O k. [1] CH;C=CLi; [2] H2O I. The product in (a), then TBDMS-CI, imidazole
Draw the product formed when pentanoic anhydride [(CH;CH,CH,CH,cO),0] is treated with each reagent. With some reagents, no reaction occurs. a. SOCI, b. H20 c. CH,OH d. NaCI e. (CH;CH),NH (excess) f. CH;CH,NH2 (excess)

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Draw the product formed when 1-bromobutane is treated with each reagent. d. The answer in (a), then H2O e. The answer in (b), then D,0 f. The answer in (a), then CH3C=CH a. Li (2 equiv) b. Mg in (CH,CH2)2O solvent c. Li (2 equiv), then Cul (0.5 equiv)