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- Explain why the bond dissociation energy for bond (a) is lower than the bond dissociation energy for bond (b). (b) AH° = 356 kJ/mol AH° = 385 kJ/molRank the indicated bonds from shortest to longest in length. a b Shortest LongestThe curved arrow notation introduced in Section 1.6B is a powerfulmethod used by organic chemists to show the movement of electronsnot only in resonance structures, but also in chemical reactions.Because each curved arrow shows the movement of two electrons,following the curved arrows illustrates what bonds are broken andformed in a reaction. Consider the following three-step process. (a) Addcurved arrows in Step [1] to show the movement of electrons. (b) Use thecurved arrows drawn in Step [2] to identify the structure of X. X isconverted in Step [3] to phenol and HCl.
- Hydrolysis of the compound represented by the figure will yield two products. Name the larger of the two products?The curved arrow notation introduced in Section 1.6 is a powerful method used by organic chemists to show the movement of electrons not only in resonance structures, but also in chemical reactions. Since each curved arrow shows the movement of two electrons, following the curved arrows illustrates what bonds are broken and formed in a reaction. Consider the following three-step process. (a) Add curved arrows in Step [1] to show the movement of electrons. (b) Use the curved arrows drawn in Step [2] to identify the structure of X. X is converted in Step [3] to phenol and HCl.Considering the indicated carbon–halogen bonds, which bond is predicted to have the higher bond dissociation energy? Which bond is stronger?
- identify which is the most and least basic among the given. refer to the number and stability of their resonance structure.Hydrocarbon A possesses a significant dipole, even though it is composed of only C—C and C—H bonds. Explain why the dipole arises and use resonance structures to illustrate the direction of the dipole. Which ring is more electron rich?The bond dissociation energy of one of the C–H bonds is considerablyless than the bond dissociation energy of the other. Which C–H bondis weaker? Offer an explanation.