Deternine the number of peaks expected observed in the vibrational spectrum ofXeF. (point group Dan). Explain your answer. DanE2C4C22C;'2C;"99i2S420,20dx² + y°, z²A1gA2gBigB2gEgAlu1111111111111-1-1111-1-1R21-111-11-111-1x² – y²1-11-111-11-11ху2-22-2(Rx, Ry)(xz, yz)11111-1-1-1-1-1A2uBluB2u111-1-1-1-1-1111-111-1-11-1-1111-11-11-11-1Eu-2-22(х, у)6---

In this question we have determine the number of vibrational modes occur in XeF4 having D4h…

Answered: Deternine the number of peaks expected…

Deternine the number of peaks expected observed in the vibrational spectrum of XeF. (point group Dan). Explain your answer.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter16: Introduction To Magnetic Spectroscopy

Section: Chapter Questions

Problem 16.16E

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Question

Deternine the number of peaks expected observed in the vibrational spectrum of
XeF. (point group Dan). Explain your answer.

Dan
E
2C4
C2
2C;'
2C;"
99
i
2S4
20,
20d
x² + y°, z²
A1g
A2g
Big
B2g
Eg
Alu
1
1
1
1
1
1
1
1
1
1
1
1
1
-1
-1
1
1
1
-1
-1
R2
1
-1
1
1
-1
1
-1
1
1
-1
x² – y²
1
-1
1
-1
1
1
-1
1
-1
1
ху
2
-2
2
-2
(Rx, Ry)
(xz, yz)
1
1
1
1
1
-1
-1
-1
-1
-1
A2u
Blu
B2u
1
1
1
-1
-1
-1
-1
-1
1
1
1
-1
1
1
-1
-1
1
-1
-1
1
1
1
-1
1
-1
1
-1
1
-1
Eu
-2
-2
2
(х, у)
6---

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