(d) Calculate the rate constant, giving the correct units for k. (e) Without doing a calculation, say how the value of k will change if the reaction is carried out at a temperature higher than 540 K? (f) What equation would you use, and what additional information would be required, in order to calculate the value of k at a temperature different from 540 K?

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 56GQ: Data in the table were collected at 540 K for the following reaction: CO(g) + NO2(g) CO2(g) + NO(g)...
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Data in the table below were collected at 540 K for the following reaction:
CO (g) + NO2(g) → CO2(g) + NO (g)
Exp
1
(f)
2
3
4
5
Initial concentration (mol/dm³)
[NO₂]
0,35 x 10-4
[CO]
5,1 x 10-4
5,1 x 10-4
5,1 x 10-4
1,0 x 10-3
1,5 x 10-3
0,70 x 10-4
0,18 x 10-4
0,35 x 10-4
0,35 x 10-4
Initial rate (mol/dm³.h)
3,4 x 10-8
6,8 x 10-8
1,7 x 10-8
6,8 x 10-8
10,2 x 10-8
(d)
Calculate the rate constant, giving the correct units for k.
(e) Without doing a calculation, say how the value of k will change if the reaction is
carried out at a temperature higher than 540 K?
What equation would you use, and what additional information would be required, in
order to calculate the value of k at a temperature different from 540 K?
Transcribed Image Text:Data in the table below were collected at 540 K for the following reaction: CO (g) + NO2(g) → CO2(g) + NO (g) Exp 1 (f) 2 3 4 5 Initial concentration (mol/dm³) [NO₂] 0,35 x 10-4 [CO] 5,1 x 10-4 5,1 x 10-4 5,1 x 10-4 1,0 x 10-3 1,5 x 10-3 0,70 x 10-4 0,18 x 10-4 0,35 x 10-4 0,35 x 10-4 Initial rate (mol/dm³.h) 3,4 x 10-8 6,8 x 10-8 1,7 x 10-8 6,8 x 10-8 10,2 x 10-8 (d) Calculate the rate constant, giving the correct units for k. (e) Without doing a calculation, say how the value of k will change if the reaction is carried out at a temperature higher than 540 K? What equation would you use, and what additional information would be required, in order to calculate the value of k at a temperature different from 540 K?
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