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- • Provide the final products P and identify the intermediates A and B. CH3I (C6H5)3P A CoHgLi ether || B C6H5CCH3 P1. Draw the structure of the major products of the following reactions HO- (1) DMSO, (COCI)2 (2) EtgN H,CrO, H. (1) KMNO,, HO", A OH (2) H,O*2. Provide a detailed mechanism for the following reaction: Br NBS light
- Predict the major products of the follow ing. (c) (a) (b) CI HO,S HNO3 Cl2, ? AICI3 FeCla H,SO, H3CO (e) (d) Br2, ? Conc. HNO, ? FeBr3a- 3. b. N OCH3 C. N Show the for reasonable Curved mechanism the reaction and make sure lone pairs + Conc HBr HBr 40c CN BrIdentify the major product of the reaction of an alkene shown below. ||| 1. Hg(OAc)2, H2O 2. NaBH4, NaOH ....... ОН || IV ОН о, ОН
- Arrange the following compounds in the increasing order of reactivity towards Conc.HNO3 & Conc.H2SO4 1. Benzene 2. Chlorobenzene 3. phenol 4. Toluene 5. Nitrobenzene A 1,2,3,4,5 B) 5,2,1,4,3 C) 5,1,4,2,3 D) 5,1,2,4,31. Draw the product of each of the following [3,3] sigmatropic rearrangements, including its stereochemistry. Ph CH3 (a) H3C. (b) Ph CH3 (c) H3C CO₂CH3 CH3 H (d)Predict the product(s) of the reaction shown. 01 " ... II, III, IV ⒸLILIILIV HBr ROOR بي بي في مي
- 3. Propose a mechanism and predict the product. Include any relevant stereochemistry. a) HCI b) CH,N2 CH,N2 = H2C-NEN HO,Draw all stereoisomers formed in each reaction. to [1] CH3LI а. [2] H2O 1m( Culi b. [1] [2] H2O [1] LIAIH4 С. с. [2] H2O [1] mCРBA d. [2] MgBr [3] H2O ..||1. Name the following alkyl halides: (a) НзС Br Br CH3 (b) I (c) Br CI CH3 CH3CHCHCHCH2ČHCH3 CH3CCH,CHCHCH, CH3CH=CHCH2CHCH3 ČH3 (d) CH2Br (e) CICH,CH2CH2C=CCH2B CH3CH2CHCH2CH2CH3 2. Predict the product(s) of the following reactions: SOCI2 (a) H3C OH (b) CH3CH2CH2CH2OH ? HBr Ether (d) CH3CH2CH(Br)CH3 Mg H20 A (c) OH B Ether PBr3 Ether