Answered: Construct the molecular orbitals of…

Construct the molecular orbitals of NH2- ion and give the initial wavefunction of LUMO using proper atomic orbitals as basis.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter13: Introduction To Symmetry In Quantum Mechanics

Section: Chapter Questions

Problem 13.74E

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Question

Construct the molecular orbitals of NH2- ion and give the initial wavefunction of LUMO using proper atomic orbitals as basis.

Expert Solution

Step 1

given:

The number of molecular orbitals is equal to number of atomic orbitals.
the overlap of two atomic orbitals give rise to two molecular orbitals.
the lowest energy molecular orbital had all the phases in the contributing P orbitals aligned in the same way.

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