Construct the 3 triplet and 1 singletwavefunction for the Li+(1s)'(2s)!configuration. Show that this open-shellsinglet is a proper eigenfunction ofandSzoperators.

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Construct the 3 triplet and 1 singlet wavefunction for the Li+ (1s)' (2s)!

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter10: Introduction To Quantum Mechanics

Section: Chapter Questions

Problem 10.34E

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Techniques and applications of quantum theory

Quantum theory, often known as quantum physics, is the foundation of modern physics and encompasses the nature and behavior of matter and energy at the atomic and molecular levels. As the exact nature and behavior of atomic and subatomic particles are impossible to determine, the laws of classical physics do not apply to this discipline. As a result, quantum field theory is primarily based on assumptions and probabilities.

Question

Construct the 3 triplet and 1 singlet
wavefunction for the Li+
(1s)'(2s)!
configuration. Show that this open-shell
singlet is a proper eigenfunction of
and
Sz
operators.

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