Constants | Periodic Table Consider the titration of a 25.0 - mL sample of 0.175 M CH3NH2 with 0.145 M HBr. Determine each of the following. Express your answer using two decimal places. pH = 11.25 Submit ΠΕΠ ΑΣΦ Part F Previous Answers Request Answer X Incorrect; Try Again; 3 attempts remaining ? the pH after adding 6.0 mL of acid beyond the equivalence point Express your answer using two decimal places.

Constants | Periodic Table Consider the titration of a 25.0 - mL sample of 0.175 M CH3NH2 with 0.145 M HBr. Determine each of the following. Express your answer using two decimal places. pH = 11.25 Submit ΠΕΠ ΑΣΦ Part F Previous Answers Request Answer X Incorrect; Try Again; 3 attempts remaining ? the pH after adding 6.0 mL of acid beyond the equivalence point Express your answer using two decimal places.

Appl Of Ms Excel In Analytical Chemistry

2nd Edition

ISBN:9781285686691

Author:Crouch

Publisher:Crouch

Chapter7: Neutralization Titrations And Graphical Representations

Section: Chapter Questions

Problem 1P

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A diprotic acid, H2B(MM=126g/moL), is determined to be a hydrate, H2B xH2O. A 10.00-g sample of this hydrate is dissolved in enough water to make 150.0 mL of solution. Twenty-five milliliters of this solution requires 48.5 mL of 0.425 M NaOH to reach the equivalence point. What is x?
A 10.00-g sample of the ionic compound NaA, where A is the anion of a weak acid, was dissolved in enough water to make 100.0 mL of solution and was then titrated with 0.100 M HCl. After 500.0 mL HCl was added, the pH was 5.00. The experimenter found that 1.00 L of 0.100 M HCl was required to reach the stoichiometric point of the titration. a. What is the molar mass of NaA? b. Calculate the pH of the solution at the stoichiometric point of the titration.
Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
A 0.400-M solution of ammonia was titrated with hydrochloric acid to the equivalence point, where the total volume was 1.50 times the original volume. At what pH does the equivalence point occur?
Which of the indicators in Fig. 14-8 could be used for the titrations in Exercises 61 and 63?
Sketch two pH curves, one for the titration of a weak acid with a strong base and one for a strong acid with a strong base. How are they similar? How are they different? Account for the similarities and the differences.
You have a solution of the weak acid HA and add some of the salt NaA to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.