Consider this three-step mechanism for a reaction: Cl₂ (g) Cl(g) + CHCl3 (g) Cl(g) + CC13(g) k₁ k₂ → k3 → k₁ 2Cl(g) (fast) HCl(g) + CC13(g) (slow) CCl4 (g) (fast)

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.70QE
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What is the predicted rate law/

Consider this three-step mechanism for a reaction:
Cl₂ (g)
Cl(g) + CHCl3 (g)
Cl(g) + CC13(g)
2C1(g)
(fast)
→ HCl(g) + CC13(g) (slow)
k3
→
CCl4 (g)
(fast)
ka
1
Transcribed Image Text:Consider this three-step mechanism for a reaction: Cl₂ (g) Cl(g) + CHCl3 (g) Cl(g) + CC13(g) 2C1(g) (fast) → HCl(g) + CC13(g) (slow) k3 → CCl4 (g) (fast) ka 1
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