Consider the reaction Mn+ + ne- ⇌ M. If ΔG*c = ΔG* + (1-α)nFE and η = E – Eeq, prove that ic = io exp[-(1-α)nFηa)/RT)].

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 12.BCP
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Consider the reaction Mn+ + ne- ⇌ M. If ΔG*c = ΔG* + (1-α)nFE and η = E – Eeq, prove that ic = io exp[-(1-α)nFηa)/RT)].
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