Consider the following reactions: Reaction 1: HC1O, + KOH → KC1O, + H;O Reaction 2: HC;H;O2 + KOH → KC;H;O2 +H;O In both reactions, 15.00 mL of 0.8116 M acid is titrated with 0.4217 M KOH. A volume of 28.87 mL of KOH is required to reach the equivalence point in both reactions. a) What is the pH of the HC1O, solution before the titration has started? (No KOH has been added.) b) What is the initial pH of HC;H;O2 solution before the titration has started? K.= 6.46 x 10-5 (Ok to use x is small.) c) What is the pH of Reaction 1 at the equivalence point? d) What is the pH of Reaction 2 at the equivalence point? e) What is the pH of Reaction 1 after 32.00 mL of KOH has been added? f) What is the pH of Reaction 2 after 18.00 mL of KOH has been added?

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Chapter16: Acid-base Equilibria
Section: Chapter Questions
Problem 16.31QP: You are given the following acidbase titration data, where each point on the graph represents the pH...
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Consider the following reactions:
Reaction 1: HCIO, + KOH → KC1O, + H;O
Reaction 2: HC;H;O2 + KOH → KC;H;O2+ H;O
In both reactions, 15.00 mL of 0.8116 M acid is titrated with 0.4217 M KOH. A volume of 28.87
mL of KOH is required to reach the equivalence point in both reactions.
a) What is the pH of the HC1O, solution before the titration has started? (No KOH has been
added.)
b) What is the initial pH of HC;H;O2 solution before the titration has started? K= 6.46 x 10-5 (Ok
to use x is small.)
c) What is the pH of Reaction 1 at the equivalence point?
d) What is the pH of Reaction 2 at the equivalence point?
e) What is the pH of Reaction 1 after 32.00 mL of KOH has been added?
f) What is the pH of Reaction 2 after 18.00 mL of KOH has been added?
Transcribed Image Text:Consider the following reactions: Reaction 1: HCIO, + KOH → KC1O, + H;O Reaction 2: HC;H;O2 + KOH → KC;H;O2+ H;O In both reactions, 15.00 mL of 0.8116 M acid is titrated with 0.4217 M KOH. A volume of 28.87 mL of KOH is required to reach the equivalence point in both reactions. a) What is the pH of the HC1O, solution before the titration has started? (No KOH has been added.) b) What is the initial pH of HC;H;O2 solution before the titration has started? K= 6.46 x 10-5 (Ok to use x is small.) c) What is the pH of Reaction 1 at the equivalence point? d) What is the pH of Reaction 2 at the equivalence point? e) What is the pH of Reaction 1 after 32.00 mL of KOH has been added? f) What is the pH of Reaction 2 after 18.00 mL of KOH has been added?
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