Consider, for example, the TLC plate pictured at right after developing and UV visualization where prior to elution, lanes A and B were spotted with 4-t-butylphenol and lanes B and C spotted with benzamide.  Which of the following must be true?  In the space provided, indicate the CORRECT answers (as 1, 2, and/or 3) then explain your reasoning for all three statements. Benzamide elutes faster than t-butylphenol. The Rf for t-butylphenol is less than that of benzamide. Benzamide is more polar than 4-t-butylphenol

EBK A SMALL SCALE APPROACH TO ORGANIC L
4th Edition
ISBN:9781305446021
Author:Lampman
Publisher:Lampman
Chapter88: Column Chromatography
Section: Chapter Questions
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Despite their structural differences, separation of mixtures of organic compounds (such as the arenes benzoic acid, 4-t-butylphenol, and benzamide) often proves difficult.  Silica gel chromatography, however, can be used with some success provided that an appropriate solvent is used to provide optimal separation.

Consider, for example, the TLC plate pictured at right after developing and UV visualization where prior to elution, lanes A and B were spotted with 4-t-butylphenol and lanes B and C spotted with benzamide.  Which of the following must be true?  In the space provided, indicate the CORRECT answers (as 1, 2, and/or 3) then explain your reasoning for all three statements.

  1. Benzamide elutes faster than t-butylphenol.
  2. The Rf for t-butylphenol is less than that of benzamide.
  3. Benzamide is more polar than 4-t-butylphenol
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