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- 2. Set the two equations equal and isolate In Ksp on one side of the equals sign by dividing both sides by (-RT). AG=RT'In Ksp=AH-TAS/-RT AG=In KSR=AH-TAS/-RT| 3. Create a graph using Excel plotting In Ksp on the y-axis and 1/T (make sure the units for temperature are Kelvin) on the x-axis. I In KSP 0 0.0029 -0.5 -1 -1.5 -2 -2.5 -3 -3.5 -4 -4.5 -5 0.003 0.0031 0.0032 1/T 0.0033 0.0034 0.0035 y=-2738x+5.075 R² = 0.9845 0.0036 a. Use the value obtained for the slope of the graph to solve for AH° using the equation derived in Question 2.3. (a) If 10.0 mL of H2SO4 (sp. Gr. 1.50, containing 48.7% of combined SO3 by weight) is diluted to 400 mL, what is the normality of the solution as an acid? (b) What volume of 6.00 M H2SO4 should be added to this in order to make the resulting mixture 1.00 N as an acid? FW's : H2SO4 = 98; SO3 = 80b) Determine the standard enthalpy change and std. Gibbs free energy change of reaction at 400 k for the reaction Co(g) +2H2(g) → CH;OH (g) At 298.15 K, AH?.co )= -26.41 kcal/mol, AH?.CH,OH()= -48.08 kcal/mol, AG.co )= -32.8079 kcal/mol, AG.CH,OH(@)= -38.69 kcal/mol, The standard heat capacity of various components is given by. CS = a + bT + cT2 + dT³, where C is in cal/mol-K and T is in K |Component b x10 e x105 d x10° a -0.291 CH3OH CO 4.55 2.186 -1.92 6.726 0.04 0.1283 -0.5307 H2 6.952 -0.0457 0.09563 -0.2079
- The emission of NO, by fossil fuel combustion can be prevented by injecting gaseous urea into the combustion mixture. The urea reduces NO (which oxidizes in air to form NO2) according to the reaction: 2 CO(NH;)»(3) + 4 NO(3) + O2(8) 4 Na(8) + 2 CO;(g) + 4 H¿O(g) Suppose that the exhaust stream of an automobile has a flow rate of 2.55 L/s at 655 Kand contains a partial pressure of NO of 12.4 torr. What total mass of urea is necessary to react complete- ly with the NO formed during 8.0 hours of driving?2HF (g) = H₂(g) + F2 (g), Ke=1.0 x 10 -95 ibrium mixture contains mostly reactants. Desktop 100 2NO(g) + O₂(g) = 2NO₂(g), Kc = 6.0 × 10¹3 Address CO(g) + Cl₂ (g) = COC12 (g), Kc = 5.0 × 10-⁹ Equilibrium mixture contains mostly products. 8:18 PM ^ Tuesday 6/21/2022 ENG INQq.1. Subject :- Account
- b) Determine the standard enthalpy change and std. Gibbs free energy change of reaction at 400 k for the reaction СO(g) +2H2(g) — CHОН (g) At 298.15 K, AH.co (0)= -26.41 kcal/mol, AH AG.co (9)= -32.8079 kcal/mol, AG cH,oh(9)= -38.69 kcal/mol, °.CH20H(9)= -48.08 kcal/mol, The standard heat capacity of various components is given by, CO = a + bT + cT² + dT³, where C, is in cal/mol-K and T is in K b x10² с х105 d x10° Соmponent CH3OH а 4.55 2.186 -0.291 -1.92 CO 6.726 0.04 0.1283 -0.5307 H2 6.952 -0.0457 0.09563 -0.2079Ca(OH)2(aq) + 2HCl(aq) → CaCl2(8) + 2H2O(1) 2. Standar... 1req For the reaction 3. AS surrou... 1req 4. AG° = A... 1req 5. AG: Pre... 1req 6. AG: Enthal... M 7. AG fro... 1req 8. Calculat... 1req 9. Calculat... 1req Question Question Question 10. Calcul... 1req AH° 30.2 kJ and AS° = 206 J/K The equilibrium constant for this reaction at 280.0 K is Assume that AH° and As are independent of temperature. Submit Answer Retry Entire Group 3 more group attempts remaining1. [15] Atmospheric pressure (P) decreases with increasing altitude (h) based on the following exponential function (with e as the base): P = Pº 1 exp Mgh RT where Pº=1 atm at h=0 (sea level) and T'is the average temperature of the atmosphere, M the molar mass of air (29 g mol-¹), and g the standard gravity. Please estimate the boiling point of water at atmospheric temperature T=293.2 K, and height h=3000 m. The heat of vaporization of water at 293.2 K is 44.22 kJ mol-
- Part F The third variable (call it v) is v=x1-cx2 + x3, where c is a constant you need to determine so that the equation for v is the SHM equation. Determine v. The solution to the equation for vis v = 2B cos(t + b). Express your answer in terms of some, all, or none of the variables 21, 22, 23, and the appropriate constants. v = ΜΕ ΑΣΦ Submit Request Answer ?2. Standard ... M 3. AS surrou*** 1req 4. AG° = AH°... M 5. AG: Pre... 1req 6. AG: Enthal... M 7. AG fro... 1req 8. Calculat... 1req question. Consider the reaction 2NO(g) + O2(g)—>2NO2(g) Using the standard thermodynamic data in the tables linked above, calculate A Grxn for this reaction at 298.15K if the pressure of each gas is 21.99 mm Hg. 9. Calculat... 1req ANSWER: kJ/mol 10. Calcul... 1req Question Question Submit Answer Visited group attempts remaining Retry Entire Group QuestionIf 10.0 mL of H2SO4 (sp. Gr. 1.50, containing 48.7% of combined SO3 by weight) is diluted to 400 mL, what is the normality of the solution as an acid? (b) What volume of 6.00 M H2SO4 should be added to this in order to make the resulting mixture 1.00N as an acid? FW's : H2SC4 = 98; SO3 = 80
