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World of Chemistry, 3rd edition

World of Chemistry, 3rd edition

3rd Edition

ISBN:9781133109655

Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste

Chapter16: Acids And Bases

Section16.1: Properties Of Acids And Bases

Problem 2RQ

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Complete the equation for the ionization of water by drawing the conjugate acid and conjugate base. Include lone pairs
of electrons.
conjugate
base
conjugate
acid
H-0-H
H-0-H
Conjugate base
Conjugate acid
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The dihydrogen phosphate ion has the ability to act as an acid in the presence of a base and as a base in the presence of an acid. What is this property called? Illustrate this behavior with water by writing BrnstedLowry acidbase reactions. Also illustrate this property by selecting a common acid and base to react with the dihydrogen phosphate ion.
1. Which of the following can act as a Lewis acid? (Hint : In each case, draw the Lewis electron dot structure of the molecule or ion. Are there lone pairs of electrons on the central atom? If so, it can be a Lewis base. Does the central atom lack an electron pair? If so, it can behave as a Lewis acid.) PH3 BCl3 H2S HS−
Use Table 14.3 to help order the following acids from strongest to weakest HNO3,H2O,NH4+,C5H5NH+
Rank the compounds in each of the following groups in order of increasing acidity or basicity, as indicated, and explain the order you assign. (a) acidity: HCI, HBr, HI. (b)basicity: H2O, OH-, H-, CI-. (c) basicity: Mg(OH)2, Si(OH)4, ClO3(OH) (Hint: Formula could also be written as HCIO4). (d) acidity: HF, H2O, NH3, CH4
Novocaine, C13H21O2N2Cl, is the salt of the base procaine and hydrochloric acid. The ionization constant for procaine is 7106. 15 a solution of novocaine acidic or basic? What are [H3O+], [OH-], and pH of a 2.0% solution by mass of novocaine, assuming that the density of the solution is 1.0 g/mL.
For oxyacids, how does acid strength depend on a. the strength of the bond to the acidic hydrogen atom? b. the electronegativity of the element bonded to the oxygen atom that bears the acidic hydrogen? c. the number of oxygen atoms? How does the strength of a conjugate base depend on these factors? What type of solution forms when a nonmetal oxide dissolves in water? Give an example of such an oxide. What type of solution forms when a metal oxide dissolves in water? Give an example of such an oxide.
For solutions of the same concentration, as acid strength increases, indicate what happens to each of the following (increases, decreases, or doesnt change). a. [H+] b. pH c. [OH] d. pOH e. Ka
Gastric juice, the digestive ?uid produced in the stomach, contains hydrochloric acid, HCl, Milk of Magnesia, a suspension of solid Mg(OH)2 in an aqueous medium, is sometimes used to neutralize-excess stomach acid. Write a complete balanced equation for the neutralization reaction, and identify the conjugate acid—base pairs.
Rank the following acids (M=0.10)in order of decreasing[ H+ ]: HFHCl HCN HCIO

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