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Chemistry: An Atoms First Approach

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter21: Organic And Biological Molecules

Section: Chapter Questions

Problem 10RQ

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Question

Complete the below statements with reference to the structures shown in the figure. Drag and drop the appropriate structure
number into each blank position.
Structure
is a primary amine, structure
is a secondary alcohol and structure
is a tertiary alkyl halide.
Structure
is a cis-alkene, structure
is a trans-alkene.
• Structure
is an E-alkene, structure
is a Zalkene.
• Structure
is an amide, structure
is an ester.
OH
OH
CH3CHy NH2
3)
8)
ce
Br
10
1 7
3
10
6
9
12 5
11| 4
2

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What is the full structure of an amine which is an isomer of ethylamine? What is the isomer called? Is it primary, secondary or tertiary?
The structure of Amines are classified as primary (1), secondary (2), and tertiary (3) based on the number of R group like providing name the parent chain, name alkyl group substitutes, name of amine by placing the alkyl groups in alphabetical order and specifying their position, followed by the name of the parent chain that concept that seemed difficult to you at first, but then after working on the concept, you were able to master it. Include a description of what made the concept difficult at first, and then discuss what you did in order to better understand the concept.
Write the systematic (IUPAC) names for the amines. The names should have the format alkanamine. H,C-N-CH-CH, systematic (IUPAC) name: NH–CH, H,C-CH-CH-CH, systematic (IUPAC) name: These compounds are secondary amines.
Which functional group is shown? 0 -N-C- Primary amine. Anhydride. Acyl. Nitrile. Amide.
(i) The table shows the structures and boiling points of three amines, which are structural isomers of C3H,N. Amine CH,CH,CH,NH, (CH,),CHNH, (CH,),N Skeletal formula `NH, NH2 Boiling point/°c 48-49°C 33-34 °C 3-4°C Explain the difference in the boiling points of the three amines. ....
4. The amine reactant can be dissolved in water. Like ammonia, amines can interact with water molecules. Draw sketches below to clearly show one solute molecule interacting with at least THREE solvent molecules. (Your Lewis structures of water molecules must be complete, with all bonds and lone pairs.) ammonia an amine with one of the butyl substituents
How can I attach an amine group (-NH2) to a carboxyl group (-COOH)? What are the experimental conditions, such as temperature, atmosphere, pH etc?
Assess the following statements. * Below is the structure of Cetirizine and the functional groups present in it. Carboxylic acid Ether Tertiary amines HO Aliphatic hydrocarbons Aromatic hydrocarbon Halogenated aromatic hydrocarbon Statement 1: The following functional groups are hydrophilic. > Carboxylic acid, Ether, Tertiary amine Statement 2: The following functional groups are hydrophobic. > Aromatic hydrocarbon, Halogenated aromatic hydrocarbon Only Statement 1 is correct/ true. Only Statement 2 is correct/ true. Both statements are correct/ true. Both statements are incorrect/ false.
Name all functional groups in the compound. HC amide; ester aldehyde; ketone ester; ketone carboxylic acid; aldehyde
Explain why it is impossible to form an amide by the condensation of a tertiary amine with a carboxylic acid.
The following molecular formulas represent saturated amine compounds or unsaturated amine compounds that contain C=C bonds. Determine whether each compound is saturated and how many C=C bonds are present. a C,H1N This amine is c and contains C=C bond(s). b C,H12N2 correct lamine is and contains C-C bond(s). € CH,N This amine is and contains C=C bond(s).
Which of the following description is the INCORRECT match to the structure? он A tertiary alcohol with the formula C,H3O. A secondary alcohol with the formula C;H,0 to Br A tertiary alkyl halide with the formula C3H1„Br. CH3 A secondary amine with the formula C3H,N

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