CHM 2410Z - Organic Chemistry I Lab 1) Consider the following molecules and choose the two represented by the spectra below. Use the IR spectra to narrow the possibilities, and then use the NMR data to confirm your choice. a. 1H NMR data: 85.8 ppm (1H, pentet) 85.0 ppm (1H, triplet) 84.9 ppm (1H, triplet) 83.6 ppm (2H, triplet) 8 2.2 ppm (2H, quartet) 82.1 ppm (1H, singlet) 8 1.7 ppm (2H, pentet) b. 1H NMR data: 8 2.4 ppm (2H, triplet) 82.1 ppm (3H, singlet) 8 1.6 ppm (2H, sextet) 80.9 ppm (3H, triplet) IR spectrum: IR/NMR Postlab IR spectrum: Relative Transmittance 0.8 0.6 0.4 0.2 0.8 0.6 0.4 0.2 3000 3000 OH H. 2000 H 2000 Wavenumber (cm-1) My H Wavenumber (cm-1) 1000 1000 OH

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter12: Structure Determination: Mass Spectrometry And Infrared Spectroscopy
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Problem 48AP: The infrared spectrum of the compound with the mass spectrum shown below lacks any significant...
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CHM 2410Z - Organic Chemistry I Lab
1) Consider the following molecules and choose the two represented by the spectra below. Use the IR
spectra to narrow the possibilities, and then use the NMR data to confirm your choice.
a. 1H NMR data:
85.8 ppm (1H, pentet)
85.0 ppm (1H, triplet)
8 4.9 ppm (1H, triplet)
83.6 ppm (2H, triplet)
8 2.2 ppm (2H, quartet)
82.1 ppm (1H, singlet)
8 1.7 ppm (2H, pentet)
b. 1H NMR data:
8 2.4 ppm (2H, triplet)
82.1 ppm (3H, singlet)
8 1.6 ppm (2H, sextet)
8 0.9 ppm (3H, triplet)
IR/NMR Postlab
i
IR spectrum:
IR spectrum:
Relative Transmittance
0.8
0.6
0.4
0.2
0.8
0.6
0.4
0.2
3000
3000
OH
H
2000
H
2000
Wavenumber (cm-1)
Wavenumber (cm-1)
H
1000
1000
OH
Transcribed Image Text:CHM 2410Z - Organic Chemistry I Lab 1) Consider the following molecules and choose the two represented by the spectra below. Use the IR spectra to narrow the possibilities, and then use the NMR data to confirm your choice. a. 1H NMR data: 85.8 ppm (1H, pentet) 85.0 ppm (1H, triplet) 8 4.9 ppm (1H, triplet) 83.6 ppm (2H, triplet) 8 2.2 ppm (2H, quartet) 82.1 ppm (1H, singlet) 8 1.7 ppm (2H, pentet) b. 1H NMR data: 8 2.4 ppm (2H, triplet) 82.1 ppm (3H, singlet) 8 1.6 ppm (2H, sextet) 8 0.9 ppm (3H, triplet) IR/NMR Postlab i IR spectrum: IR spectrum: Relative Transmittance 0.8 0.6 0.4 0.2 0.8 0.6 0.4 0.2 3000 3000 OH H 2000 H 2000 Wavenumber (cm-1) Wavenumber (cm-1) H 1000 1000 OH
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