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camparing vanious alkyl halides reactivity toward SN1 reactions using water as a nucleopnile Entry # Alko| halide K(x101min") 0.2231 t 0.0041 Eq(kcsI) COHS CH 2 C1 Cetts CH2Br coHs CHCI 2 Ce Hs CHCIBr Cuts CCI3 CoHs CC12 Br A 212214) 21.2 2. 5684I 0.085 19.1 2.214 E 0.037 23.3 31.08 1 0.19 110.5 0.9 4 21.9 20.5 19.2 reaction was dame in 50%. aqueOUS acetune at 30°C reaction n scherre fur entry #1 H2O -> acetane a) which is a better leaving group, wby? b) unat isthe structure of the intermediale of the reaction in entry #3 c) Does the presence ofa secund halogen Increase or decrcase the stability ot carbocation.

camparing vanious alkyl halides reactivity toward SN1 reactions using water as a nucleopnile Entry # Alko| halide K(x101min") 0.2231 t 0.0041 Eq(kcsI) COHS CH 2 C1 Cetts CH2Br coHs CHCI 2 Ce Hs CHCIBr Cuts CCI3 CoHs CC12 Br A 212214) 21.2 2. 5684I 0.085 19.1 2.214 E 0.037 23.3 31.08 1 0.19 110.5 0.9 4 21.9 20.5 19.2 reaction was dame in 50%. aqueOUS acetune at 30°C reaction n scherre fur entry #1 H2O -> acetane a) which is a better leaving group, wby? b) unat isthe structure of the intermediale of the reaction in entry #3 c) Does the presence ofa secund halogen Increase or decrcase the stability ot carbocation.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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camparing vanious alkyl halides reactivity toward SN1 reactions using water as a nucleopnile Entry # Alko| halide K(x101min") 0.2231 t 0.0041 Eq(kcsI) COHS CH 2 C1 Cetts CH2Br coHs CHCI 2 Ce Hs CHCIBr Cuts CCI3 CoHs CC12 Br A 212214) 21.2 2. 5684I 0.085 19.1 2.214 E 0.037 23.3 31.08 1 0.19 110.5 0.9 4 21.9 20.5 19.2 reaction was dame in 50%. aqueOUS acetune at 30°C reaction n scherre fur entry #1 H2O -> acetane
Transcribed Image Text:camparing vanious alkyl halides reactivity toward SN1 reactions using water as a nucleopnile Entry # Alko| halide K(x101min") 0.2231 t 0.0041 Eq(kcsI) COHS CH 2 C1 Cetts CH2Br coHs CHCI 2 Ce Hs CHCIBr Cuts CCI3 CoHs CC12 Br A 212214) 21.2 2. 5684I 0.085 19.1 2.214 E 0.037 23.3 31.08 1 0.19 110.5 0.9 4 21.9 20.5 19.2 reaction was dame in 50%. aqueOUS acetune at 30°C reaction n scherre fur entry #1 H2O -> acetane
a) which is a better leaving group, wby? b) unat isthe structure of the intermediale of the reaction in entry #3 c) Does the presence ofa secund halogen Increase or decrcase the stability ot carbocation.
Transcribed Image Text:a) which is a better leaving group, wby? b) unat isthe structure of the intermediale of the reaction in entry #3 c) Does the presence ofa secund halogen Increase or decrcase the stability ot carbocation.
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