Both [Co(CN)6]3- and [Co(H2O)6]3+ have and octahedral geometry around the metal centers. Applying Valance Bond Theory determine the type of hybirdization on the metal center.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Both [Co(CN)6]3- and [Co(H2O)6]3+ have and octahedral geometry around the metal centers. Applying Valance Bond Theory determine the type of hybirdization on the metal center.

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Introduction

Valence bond theory is a model used to explain the bonding behavior of atoms in molecules. It is based on the idea that when two atoms interact, they are held together by shared electrons in the form of "bonds". The theory predicts the number and type of bonds formed between two atoms, as well as the shape they form.

The theory is based on the assumption that the electrons in a molecule are localized, instead of delocalized (as in an orbital hybridization model). This means that the electrons are localized around one atom and are not spread out in a continuous cloud. This means that the bonding interactions between two atoms can be thought of as the overlap of two sets of orbitals, each with its own electron density. The strength of the bond is determined by the overlap of the electron densities, and the nature of the bond (ionic, covalent, etc.) is determined by the type of orbitals involved.

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