(b). (i). The electronic absorption spectrum of aqueous [Ti(OH2)6]?* (stable under acidic conditions) exhibits two well-separated bands at 430 and 650 nm. These two bands indicate the appearance of 'd-d' transitions, whereas the aqueous [Ti(OH2)6]3+ exhibits one absorption band at 490 nm with a shoulder at 580 nm. By drawing the splitting orbital diagram, explain clearly the difference between these absorption bands of [Ti(OH2)6]?+ and [Ti(OH2)s]3+.
(b). (i). The electronic absorption spectrum of aqueous [Ti(OH2)6]?* (stable under acidic conditions) exhibits two well-separated bands at 430 and 650 nm. These two bands indicate the appearance of 'd-d' transitions, whereas the aqueous [Ti(OH2)6]3+ exhibits one absorption band at 490 nm with a shoulder at 580 nm. By drawing the splitting orbital diagram, explain clearly the difference between these absorption bands of [Ti(OH2)6]?+ and [Ti(OH2)s]3+.
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter19: Complex Ions
Section: Chapter Questions
Problem 4QAP: Platinum(II) forms many complexes, among them those with the following ligands. Give the formula and...
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Kindly answer this question i & ii
![(b). (i).
The electronic absorption spectrum of aqueous [Ti(OH2)6]?+
(stable under acidic conditions) exhibits two well-separated
bands at 430 and 650 nm. These two bands indicate the
appearance of 'd-d' transitions, whereas the aqueous
[Ti(OH2)6]3+ exhibits one absorption band at 490 nm with a
shoulder at 580 nm. By drawing the splitting orbital diagram,
explain clearly the difference between these absorption bands
of [Ti(OH2)6]?* and [Ti(OH2)6]*.
(ii). Determine whether these octahedral complexes, [CrF6]“,
[Fe(CN)6]4 and [Fe(CN)6]³ will be affected by the Jahn-Teller
distortion.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd67fd779-9a67-45d3-a93e-6c4ca8de8554%2Fbf6e83c3-515a-4946-a9e0-3d8a2eb5286b%2Fqo1deik_processed.jpeg&w=3840&q=75)
Transcribed Image Text:(b). (i).
The electronic absorption spectrum of aqueous [Ti(OH2)6]?+
(stable under acidic conditions) exhibits two well-separated
bands at 430 and 650 nm. These two bands indicate the
appearance of 'd-d' transitions, whereas the aqueous
[Ti(OH2)6]3+ exhibits one absorption band at 490 nm with a
shoulder at 580 nm. By drawing the splitting orbital diagram,
explain clearly the difference between these absorption bands
of [Ti(OH2)6]?* and [Ti(OH2)6]*.
(ii). Determine whether these octahedral complexes, [CrF6]“,
[Fe(CN)6]4 and [Fe(CN)6]³ will be affected by the Jahn-Teller
distortion.
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