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Another useful aspect of Pd(0)-catalyzed allylic alkylation is the ability to take reactants that are meso and desymmetrize them in the resulting products through the addition of a chiral ligand for the Pd metal. Draw the two n-allylic complexes formed in this reaction of the following reactant with PdL,. Describe why chirality in a ligand L would influence the preference for one of these complexes over the other. AcO OAc

Another useful aspect of Pd(0)-catalyzed allylic alkylation is the ability to take reactants that are meso and desymmetrize them in the resulting products through the addition of a chiral ligand for the Pd metal. Draw the two n-allylic complexes formed in this reaction of the following reactant with PdL,. Describe why chirality in a ligand L would influence the preference for one of these complexes over the other. AcO OAc

Organic Chemistry
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter24: Catalytic Carbon-carbon Bond Formation
Section: Chapter Questions
Problem 24.22P
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Another useful aspect of Pd(0)-catalyzed allylic alkylation is the ability to take reactants that are meso and desymmetrize them in the resulting products through the addition of a chiral ligand for the Pd metal. Draw the two n-allylic complexes formed in this reaction of the following reactant with PdL,. Describe why chirality in a ligand L would influence the preference for one of these complexes over the other. AcO OAc
Transcribed Image Text:Another useful aspect of Pd(0)-catalyzed allylic alkylation is the ability to take reactants that are meso and desymmetrize them in the resulting products through the addition of a chiral ligand for the Pd metal. Draw the two n-allylic complexes formed in this reaction of the following reactant with PdL,. Describe why chirality in a ligand L would influence the preference for one of these complexes over the other. AcO OAc
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