An electrochemical cell is given with a cell reaction of Pb²⁺ + Cd → Pb + Cd²⁺ at 25°C with ion concentrations of [Cd²⁺] = 2 M, and [Pb²⁺] = 1.49×10⁻⁹ M. Used the photo as a reference. 1. What can be said of the reaction at the specified concentration of ions? 2. What is the equilibrium constant for the reaction?

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter17: Electrochemistry And Its Applications
Section17.4: Voltaic Cells And Cell Potential
Problem 17.4PSP: Given this reaction, its standard potential, and the standard half-cell potential of 0.34 V for the...
icon
Related questions
Question

An electrochemical cell is given with a cell reaction of Pb²⁺ + Cd → Pb + Cd²⁺ at 25°C with ion concentrations of [Cd²⁺] = 2 M, and [Pb²⁺] = 1.49×10⁻⁹ M. Used the photo as a reference.

1. What can be said of the reaction at the specified concentration of ions?
2. What is the equilibrium constant for the reaction?

 
 
 
 
 
 
 
 
Use R = 8.31447 J/mol K and F = 96,485 C/mol e-.
Standard reduction potentials for some common metals - for aqueous
solutions of ions at 1.0 M concentration at 25 °C and H2 gas at 1.0 atm
pressure and 25°C
Reduction Half-Cell Equation
Li+ + 1e →→→ Li
K+ + 1e-
→ K
Ba2+ + 2e → Ba
Ca2+ + 2e → Ca
Na + 1e O Na
Mg2+ + 2e
→→ Mg
Al3+ + 3e → Al
Zn2+ + 2e- → Zn
Cr³+ + 3e → Cr
Fe2+ + 2e
→ Fe
Cd²+ + 2e-
Ni2+ + 2e
Sn²+ + 2e
sn
Pb2+ + 2e → Pb
→ Cd
→ Ni
2 H+ + 2e → H2
Cu2+ + 2e
→ Cu
Hg2+ + 2e → 2 Hg
Ag+ +1e
Ag
Hg2+ + 2e →→ Hg
Au³+ + 3e → Au
E° (v)
-3.04
-2.92
-2.91
-2.87
-2.71
-2.36
-1.66
-0.76
-0.74
-0.44
-0.40
-0.25
-0.14
-0.13
0.00
+0.34
+0.79
+0.80
+0.85
+1.42
Transcribed Image Text:Use R = 8.31447 J/mol K and F = 96,485 C/mol e-. Standard reduction potentials for some common metals - for aqueous solutions of ions at 1.0 M concentration at 25 °C and H2 gas at 1.0 atm pressure and 25°C Reduction Half-Cell Equation Li+ + 1e →→→ Li K+ + 1e- → K Ba2+ + 2e → Ba Ca2+ + 2e → Ca Na + 1e O Na Mg2+ + 2e →→ Mg Al3+ + 3e → Al Zn2+ + 2e- → Zn Cr³+ + 3e → Cr Fe2+ + 2e → Fe Cd²+ + 2e- Ni2+ + 2e Sn²+ + 2e sn Pb2+ + 2e → Pb → Cd → Ni 2 H+ + 2e → H2 Cu2+ + 2e → Cu Hg2+ + 2e → 2 Hg Ag+ +1e Ag Hg2+ + 2e →→ Hg Au³+ + 3e → Au E° (v) -3.04 -2.92 -2.91 -2.87 -2.71 -2.36 -1.66 -0.76 -0.74 -0.44 -0.40 -0.25 -0.14 -0.13 0.00 +0.34 +0.79 +0.80 +0.85 +1.42
Expert Solution
steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Electrolysis
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Chemistry: An Atoms First Approach
Chemistry: An Atoms First Approach
Chemistry
ISBN:
9781305079243
Author:
Steven S. Zumdahl, Susan A. Zumdahl
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781133611097
Author:
Steven S. Zumdahl
Publisher:
Cengage Learning
General Chemistry - Standalone book (MindTap Cour…
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning
Chemistry: Principles and Practice
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning