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- Shown below is the reaction of a diene with an electrophile. Two products are formed.Buta-1,3-diene reacts with Br2 to yield a mixture of 1,2- and 1,4-addition products. Show the structures of both.Complete the following by drawing products for a and b, and also identify the diene and dienophile in each one.
- For the following dienes, predict the product and draw the full arrow pushing mechanism. Label each product as thermodynamic or kinet5) A diene is a compound that contains two double bonds. When 1,3-cyclohexadiene reacts with DBr (analogous to HBr) the following is observed. Br DBr major product not formed a) Using words and structures, explain this distribution of products. b) Another product is formed in this reaction (shown below). Write a mechanism (with proper curved arrows) to explain its formation. D BrDraw the structure of the conjugated diene that will react with one equivalent of HBr to yield a racemic mixture of 3-bromocyclohexene.
- 6. When the DIESTER shown below is treated as shown, TWO products are formed. Draw the structures of these products and provide a detailed mechanism to account for their formation. OMe 1. NaOEt/ĘTOH Two Products OMe Product 1 Product 2 Mechanism: CS Scanned with CamScannerShow the detailed mechanism of this in 3D structure, and predict the major regioisomer and the major stereoisomer with a stepwise explanation. show the final major product in Newman projection.Provide mechanistic pathway for each step and the products based on the reagents selected. Diels Alders reactions to consider the formation of the products stated below. Product in step 1 is used for step 2. Product instep 2 is used for step 3. Indicate any required stereochemistry (E, Z, R, S).Step 1: 3-bromo-3-methylbut-1-ene with sodium ethoxideStep 2: addition of maleic anhydride and heatStep 3: hydrogen gas bubbling with palladium metal
- Show the detailed mechanism. show all structures in 3D, and predict the major regioisomer and major stereoisomer with explanation step by step. show product in Newman projection.7. Predict the product of the Diels-Alder reaction of this compound with 1,3-cyclohexadiene (not shown). You do not have to consider stereochemistry. Bicyclic templates are shown to the right.Treatment of 1,2-dibromoethane with the dithiolate dianion shown in the reaction below leads to two products as shown. Draw the structure for each molecular formula and provide a detailed mechanism for the formation of both products.