a. Reaction condition for the reduction of an alkyne to a cis-alkene. Markovnikov addition of water to a double bond, with no carbocation rearrangement. Anti-Markovnikov addition of HBr to a double bond. nti-Markovnikov addition of water to a double bond. action condition to change 1,2-dimethylcyclohexene into cis-1,2-dimethylcyclohexane.

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter6: An Overview Of Organic Reactions
Section6.SE: Something Extra
Problem 36AP
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The following statements (parts a-e) describe a specific reaction along with its regio- and/or stereo-control. Match the reaction
conditions below (1-8) that correctly corresponds to the statement. Answer with 1, 2, 3, 4, 5, 6, 7, or 8.
1. Hg(OAC)2, H₂O
2. NaBH
Condition 1
Br
fioh 5
1. BH3, THF
2. H₂O₂, H₂O, OH-
Condition 2
H₂O+
Condition 6
en condition for the reduction of on alkung to a
fo
الم منم م م مصحلام
de
H₂
Pd/C
Condition 3
HBr
Condition 7
alkono
11
to da
H₂
Lindlar's cat.
Condition 4
NaNha
Condition 8
hp
Transcribed Image Text:The following statements (parts a-e) describe a specific reaction along with its regio- and/or stereo-control. Match the reaction conditions below (1-8) that correctly corresponds to the statement. Answer with 1, 2, 3, 4, 5, 6, 7, or 8. 1. Hg(OAC)2, H₂O 2. NaBH Condition 1 Br fioh 5 1. BH3, THF 2. H₂O₂, H₂O, OH- Condition 2 H₂O+ Condition 6 en condition for the reduction of on alkung to a fo الم منم م م مصحلام de H₂ Pd/C Condition 3 HBr Condition 7 alkono 11 to da H₂ Lindlar's cat. Condition 4 NaNha Condition 8 hp
Condition 5
a. Reaction condition for the reduction of an alkyne to a cis-alkene.
b. Markovnikov addition of water to a double bond, with no carbocation rearrangement.
c. Anti-Markovníkov addition of HBr to a double bond.
Anti-Markovnikov addition of water to a double bond.
eaction condition to change 1,2-dimethylcyclohexene into cis-1,2-dimethylcyclohexane.
14
$4
"do
96
5
E
9+
by
Transcribed Image Text:Condition 5 a. Reaction condition for the reduction of an alkyne to a cis-alkene. b. Markovnikov addition of water to a double bond, with no carbocation rearrangement. c. Anti-Markovníkov addition of HBr to a double bond. Anti-Markovnikov addition of water to a double bond. eaction condition to change 1,2-dimethylcyclohexene into cis-1,2-dimethylcyclohexane. 14 $4 "do 96 5 E 9+ by
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