A student makes a buffer from 100 mL of 0.10 M formic acid (HCOOH) and 100 mL of 0.10 M potassium formate (KCHOO). Upon addition of 20 mL of 1M NaOH solution, the student observes the pH is significantly higher than the original pH of the buffer, and concludes the buffer was defective. Is the student correct? What is the buffer capacity?

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter16: Reactions Between Acids And Bases
Section: Chapter Questions
Problem 16.78QE
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A student makes a buffer from 100 mL of 0.10 M formic acid (HCOOH) and 100 mL of 0.10 M potassium formate (KCHOO).

Upon addition of 20 mL of 1M NaOH solution, the student observes the pH is significantly higher than the original pH of the buffer, and concludes the buffer was defective.

Is the student correct? What is the buffer capacity?

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