A solution of Na3AsO4 is added dropwise to a solution that is 0.0576 M in Cu2+ and 0.000398 M in Ag+. The Ksp of Cu3(AsO4)2 is 7.95e-36. The Ksp of Ag3AsO4 is 1.03e-22. (a) What concentration of AsO43- is necessary to begin precipitation? (Neglect volume changes.) [AsO43-] = ______M. (b) Which cation precipitates first? Cu2+ Ag+ (c) What is the concentration of AsO43- when the second cation begins to precipitate? [AsO43-] = _____M.
A solution of Na3AsO4 is added dropwise to a solution that is 0.0576 M in Cu2+ and 0.000398 M in Ag+. The Ksp of Cu3(AsO4)2 is 7.95e-36. The Ksp of Ag3AsO4 is 1.03e-22. (a) What concentration of AsO43- is necessary to begin precipitation? (Neglect volume changes.) [AsO43-] = ______M. (b) Which cation precipitates first? Cu2+ Ag+ (c) What is the concentration of AsO43- when the second cation begins to precipitate? [AsO43-] = _____M.
Chapter11: Solving Equilibrium Problems For Complex Systems
Section: Chapter Questions
Problem 11.16QAP
Related questions
Question
A solution of Na3AsO4 is added dropwise to a solution that is 0.0576 M in Cu2+ and 0.000398 M in Ag+.
The Ksp of Cu3(AsO4)2 is 7.95e-36.
The Ksp of Ag3AsO4 is 1.03e-22.
(a) What concentration of AsO43- is necessary to begin precipitation? (Neglect volume changes.)
[AsO43-] = ______M.
(b) Which cation precipitates first?
Cu2+
Ag+
Ag+
(c) What is the concentration of AsO43- when the second cation begins to precipitate?
[AsO43-] = _____M.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 6 steps
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
General Chemistry - Standalone book (MindTap Cour…
Chemistry
ISBN:
9781305580343
Author:
Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:
Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:
9781305079113
Author:
David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Introductory Chemistry: An Active Learning Approa…
Chemistry
ISBN:
9781305079250
Author:
Mark S. Cracolice, Ed Peters
Publisher:
Cengage Learning