A saturated-liquid mixture of 70 mol% benzene and 30 mol% toluene, whose relative volatility is 2.5, is to be distilled at 1 atm to produce a distillate of 80 mol% benzene.Continuous distillation in a column containing one equilibrium plate. The feed is sent to the direct-heated still, from which residue is withdrawn continuously. The vapors from the plate enter the top of a helically coiled partial condenser that discharges into a trap. The liquid from the trap is returned to the plate, while the uncondensed vapor is condensed to form a distillate containing 80 mol% benzene. The molar ratio of reflux to product is 0.5.calculate and tabulate: (a) moles of distillate per 100 moles of feed, (b) moles of total vapor generated per mole of distillate, and (c) mol% benzene in the residue. (d) For each part, construct a y–x diagram. On this, indicate the compositions of the overhead product, the reflux, and the composition of the residue.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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A saturated-liquid mixture of 70 mol% benzene and 30 mol% toluene, whose relative volatility is 2.5, is to be distilled at 1 atm to produce a distillate of 80 mol% benzene.Continuous distillation in a column containing one equilibrium plate. The feed is sent to the direct-heated still, from which residue is withdrawn continuously. The vapors from the plate enter the top of a helically coiled partial condenser that discharges into a trap. The liquid from the trap is returned to the plate, while the uncondensed vapor is condensed to form a distillate containing 80 mol% benzene. The molar ratio of reflux to product is 0.5.calculate and tabulate: (a) moles of distillate per 100 moles of feed, (b) moles of total vapor generated per mole of distillate, and (c) mol% benzene in the residue. (d) For each part, construct a y–x diagram. On this, indicate the compositions of the overhead product, the reflux, and the composition of the residue. 

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