APart BChoose the structure with highlighted donor atoms.OH₂NH2=0::0:O H₂NTH₂NH₂H₂0:OH₂NH₂!ö:!ö::0:SubmitRequest AnswerPart CGive the coordination number of the metal in the complex.Express your answer as an integer.ΤΟ ΑΣΦ->0i ?MacBook Air

Step 1:A ligand is donor atoms which donates one or more electron pair to metal and forms…

Answered: A Part B Choose the structure with…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes

Section: Chapter Questions

Problem 31P

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Two different compounds are known with the formula Pd(py)2Cl2, but there is only one compound with the formula Zn(py)2Cl2. The symbol py is for pyridine, a mono-dentate ligand. Explain the differences in the Pd and Zncompounds.
a. In the absorption spectrum of the complex ion Cr(NCS)63, there is a band corresponding to the absorption of a photon of light with an energy of 1.75 104 cm-1. Given 1 cm1 = 1.986 1023 J, what is the wavelength of this photon? b. The CrNC bond angle in Cr(NCS)63 is predicted to be 180. What is the hybridization of the N atom in the Ncs- ligand when a Lewis acid-base reaction occurs between Cr3+ and NCs- that would give a 180 CrNC bond angle? Cr(NCS)63 undergoes substitution by ethylenediamine (en) according to the equation Cr(NCS)63+2enCr(NCS)2(en)2++4NCS Does Cr(NCS)2(en)2+ exhibit geometric isomerism? Does Cr(NCS)2(en)2+ exhibit optical isomerism?
Trimethylphosphine, P(CH3)3, can act as a ligand by donating the lone pair of electrons on the phosphorus atom. If trimethylphosphine is added to a solution of nickel(Il) chloride in acetone, a blue compound that has a molecular mass of approximately 270 g and contains 21.5% Ni, 26.0% Cl, and 52.5% P(CH3)3 can be isolated. This blue compound does not have any isomeric forms. What are the geometry and molecular formula of the blue compound?
A 3.03-g petroleum specimen was decomposed by wet ashing and subsequently diluted to 500 mL in a volumetric flask. Cobalt was determined by treating 25.00-mL aliquots of this diluted solution as follows: Assume that the Co(II)-ligand chelate obeys Beer’s law, and calculate the percentage of cobalt in the original sample.
Give the coordination number for each metal ion in the following compounds: (a) [Co(CO3)3]3- (note that CO32- is bidentate in this complex). (b) [Cu(NH3)4]2+. (c) [Co(NH3)4Br2]2(SO4)3. (d) [Pt(NH3)4][PtCl4]. (e) [Cr(en)3](NO3)3. (f) [Pd(NH3)2Br2] (square planar). (g) K3[Cu(Cl)5]. (h) [Zn(NH3)2Cl2]
Give the coordination numbers and write the formulas for each of the following, including all isomers where appropriate: (a) tetrahydroxozincate(ll) ion (tetrahedral). (b) hexacyanopalladate(IV) ion. (c) dichlomaurate(I) ion (note that aurum is Latin for "gold"). (d) diamminedichloroplatinum(Il). (e) potassium diamminetetrachlorochromate(III). (f) hexaamminecobalt(III) hexacyanochromate(III). (g) dibromobis(ethylenediamine) cobalt(III) nitrate
Which of the following statement(s) is( are) true? a. The coordination number of a metal ion in an octahedral complex ion is 8. b. All tetrahedral complex ions are low-spin. c. The formula for triaquatrianuninechromiwn(III) sulfate is [Cr(H2O)3(NH3)](SO4)3. d. The electron configuration of Hf2+ is [Xe]4f126s2. e. Hemoglobin contains Fe3+.
Would you expect the complex [Co(en)3]Cl3 to have any unpaired electrons? Any isomers?
define atoms, molecules, ions, the structure of atoms and chemical bonding A student has succeeded in identifying 2 types of complex compounds, the first compound (Odd Student ID) has percentage of Pt 52.6%; N 7.6%; H 1.63%; and 38.2% Cl with a central atomic charge of +4, while the second compound has composition of Co 22.0%; N 31.4%; H 6.78%; and 39.8% Cl with a central atomic charge of +3. a) Determine the empirical formula of both complex compounds! b) Draw the chemical structure and give name of both complex compounds!
A complexes of the formula [Co(en),CI]CI prepared by the following procedure Dissolve 40 g of CoCl, 6H2O in 125 ml of distilled H,O Dissove 16 g of en in 135 ml of distiled H.O Combine the two solutions Air is farced through the solution for 8 hr. The reaction solution is placed in a targe evaporating dish and 975 ml of conc HCI are added. Concentrate the solution to half of its volume using a steam bath Cool the remaining solution in an ice bath The product collected and washed by suction filtration Calculate the theoretical yield Select one O a 48.0g b. 41.49 O 35 60 Od 38.0 g e 39 69 Nest pae
A student has succeeded in identifying 2 types of complex compounds, the first compound (Odd Student ID) has percentage of Pt 52.6%; N 7.6%; H 1.63%; and 38.2% Cl with a central atomic charge of +4, while the second compound has composition of Co 22.0%; N 31.4%; H 6.78%; and 39.8% Cl with a central atomic charge of +3. a) Determine the empirical formula of both complex compounds! b) Draw the chemical structure and give name of both complex compounds!

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A Part B Choose the structure with highlighted donor atoms. OH₂N H2 =0: :0: O H₂NT H₂N H₂ H₂ 0: OH₂N H₂ !ö: !ö: :0: Submit Request Answer Part C Give the coordination number of the metal in the complex. Express your answer as an integer. ΤΟ ΑΣΦ -> 0 i ? MacBook Air