a) Give a curved arrow-pushing mechanism for the following reactions. 1) NaOHag 2) Cl2 ola CH3 CH3 + NacI b) Provide the structures of all products from this crossed aldol condensation reaction. ola. „CH3 1) НО- *CH3 2) HO¯, heat (- H20) c) Indicate the most acidic alpha hydrogen(s) "H" in the ketone/aldehyde reagents in 6b. olm .CH3 CH3 Vs H

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter11: Ethers, Epoxides, And Sulfides
Section: Chapter Questions
Problem 11.18P
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6.
a) Give a curved arrow-pushing mechanism for the following reactions.
1) NaOHag
2) Cl2
CH3
CH3
+ NaCI
b) Provide the structures of all products from this crossed aldol condensation reaction.
„CH3
1) НО-
`CH3
H
2) НО, heat
(- H20)
c) Indicate the most acidic alpha hydrogen(s) “H" in the ketone/aldehyde reagents in 6b.
olo
„CH3
VS
CH3
H
Transcribed Image Text:6. a) Give a curved arrow-pushing mechanism for the following reactions. 1) NaOHag 2) Cl2 CH3 CH3 + NaCI b) Provide the structures of all products from this crossed aldol condensation reaction. „CH3 1) НО- `CH3 H 2) НО, heat (- H20) c) Indicate the most acidic alpha hydrogen(s) “H" in the ketone/aldehyde reagents in 6b. olo „CH3 VS CH3 H
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