(a) Distinguish between reactions rate and reaction mechanism (b) The following data were obtained for the reaction I'aq + OCI' aq→ IO' + CIaq Initiel Det

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.63QE
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(a) Distinguish between reactions rate and reaction mechanism (b) The following data were
obtained for the reaction I'aq + OCI aq→ IO" + CI'aq
[OCI ]
[1]
mol/dm3
Initial Rate
mol/dm3
mol/dm?/s
1.8 x 103
3.6 х 103
2.1 x 103 5.4 x 105
2.1 x 103 10.8 x 10$
I
II
I 1.8х 103
(i)What is the order of the reaction with respect to [I'] and [OCI]
(ii) Calculate the rate constant using the results of experiment II
(iii) What is the rate law or rate equation for this reaction?
6.3х 103
4.9 x 104
Transcribed Image Text:(a) Distinguish between reactions rate and reaction mechanism (b) The following data were obtained for the reaction I'aq + OCI aq→ IO" + CI'aq [OCI ] [1] mol/dm3 Initial Rate mol/dm3 mol/dm?/s 1.8 x 103 3.6 х 103 2.1 x 103 5.4 x 105 2.1 x 103 10.8 x 10$ I II I 1.8х 103 (i)What is the order of the reaction with respect to [I'] and [OCI] (ii) Calculate the rate constant using the results of experiment II (iii) What is the rate law or rate equation for this reaction? 6.3х 103 4.9 x 104
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