A container with volume 0.2 m' contains of 2.5 moles of oxygen gas. Given that the molar mass of oxygen molecule is 16 g/mol and the most probable speed is 576 m/s. Consider the gas as an ideal gas, find (a) the root mean square speed of each molecule. (b) the temperature of the oxygen gas, (c) the pressure of the oxygen gas, (d) the number of mole of molecules which the speed is in the range of 400-420 m/s. 3 Mv2 v2e 2RT M Maxwell distribution function P(v) = 4n 2TRT

A container with volume 0.2 m' contains of 2.5 moles of oxygen gas. Given that the molar mass of oxygen molecule is 16 g/mol and the most probable speed is 576 m/s. Consider the gas as an ideal gas, find (a) the root mean square speed of each molecule. (b) the temperature of the oxygen gas, (c) the pressure of the oxygen gas, (d) the number of mole of molecules which the speed is in the range of 400-420 m/s. 3 Mv2 v2e 2RT M Maxwell distribution function P(v) = 4n 2TRT

Principles of Physics: A Calculus-Based Text

5th Edition

ISBN:9781133104261

Author:Raymond A. Serway, John W. Jewett

Publisher:Raymond A. Serway, John W. Jewett

Chapter16: Temperature And The Kinetic Theory Of Gases

Section: Chapter Questions

Problem 15OQ

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Cylinder A contains oxygen (O2) gas, and cylinder B contains nitrogen (N2) gas. If the molecules in the two cylinders have the same rms speeds, which of the following statements is false? (a) The two gases haw different temperatures. (b) The temperature of cylinder B is less than the temperature of cylinder A. (c) The temperature of cylinder B is greater than the temperature of cylinder A. (d) The average kinetic energy of the nitrogen molecules is less than the average kinetic energy of the oxygen molecules.
One cylinder contains helium gas and another contains krypton gas at the same temperature. Mark each of these statements true, false, or impossible to determine from the given information. (a) The rms speeds of atoms in the two gases are the same. (b) The average kinetic energies of atoms in the two gases are the same. (c) The internal energies of 1 mole of gas in each cylinder are the same. (d) The pressures in the two cylinders ale the same.
On a hot summer day, the density of air at atmospheric pressure at 35.0C is 1.1455 kg/m3. a. What is the number of moles contained in 1.00 m3 of an ideal gas at this temperature and pressure? b. Avogadros number of air molecules has a mass of 2.85 102 kg. What is the mass of 1.00 m3 of air? c. Does the value calculated in part (b) agree with the stated density of air at this temperature?
Find (a) the most probable speed, (b) the average speed, and (c) the rms speed for nitrogen molecules at 295 K.
One process for decaffeinating coffee uses carbon dioxide ( M=44.0 g/mol) at a molar density of about 14,0 mol/m3 and a temperature of about 60 . (a) Is CO2 a solid, liquid, gas, or supercritical fluid under those conditions? (b) The van der Waals constants for carbon dioxide are a=0.3658 Pa m6/mol2 and b=4.286105 m3/mol. Using the van der Waals equation, estimate pressure of CO2 at that temperature and density. `
Consider the Maxwell-Boltzmann distribution function plotted in Problem 28. For those parameters, determine the rms velocity and the most probable speed, as well as the values of f(v) for each of these values. Compare these values with the graph in Problem 28. 28. Plot the Maxwell-Boltzmann distribution function for a gas composed of nitrogen molecules (N2) at a temperature of 295 K. Identify the points on the curve that have a value of half the maximum value. Estimate these speeds, which represent the range of speeds most of the molecules are likely to have. The mass of a nitrogen molecule is 4.68 1026 kg. Equation 20.18 can be used to find the rms velocity given the temperature, Boltzmanns constant, and the mass of the atom or molecule. The mass of a nitrogen molecule is 4.68 1026 kg. vrms=3kBTm=3(1.381023J/K)4.681026kg=511m/s Using the results of Problem 28 and the rms velocity, we can calculate the value of f(v). f(vrms) = (3.11 108)(511)2 e(5.75106(511)2) = 0.00181 The most probable speed, for which this function has its maximum value, is given by Equation 20.20. vmp=2kBTm=2(1.381023J/K)(295K)4.681026kg=417m/s f(vmp) = (3.11108)(417)2 e(5.75106(417)2) = 0.00199 We plot these points on the speed distribution. The most probable speed is indeed at the peak of the distribution function. Since the function is not symmetric, the rms velocity is somewhat higher than the most probable speed. Figure P20.29ANS
An ideal gas is contained in a vessel at 300 K. The temperature of the gas is then increased to 900 K. (i) By what factor does the average kinetic energy of the molecules change, (a) a factor of 9, (b) a factor of 3, (c) a factor of 3, (d) a factor of 1, or (e) a factor of 13? Using the same choices as in part (i), by what factor does each of the following change: (ii) the rms molecular speed of the molecules, (iii) the average momentum change that one molecule undergoes in a collision with one particular wall, (iv) the rate of collisions of molecules with walls, and (v) the pressure of the gas?
In the text, it was shown that N/V=2.681025m3 for gas at STP. (a) Show that this quantity is equivalent to N/V=2.681019cm3, as stated. (b) About how many atoms are mere in one m3 (a cubic micrometer) at STP? (c) What does your answer to part (b) imply about the separation of Mama and molecules?
Two containers hold an ideal gas at the same temperature and pressure. Both containers hold the same type of gas, but container B has twice the volume of container A. (i) What is the average translational kinetic energy per molecule in container B? (a) twice that of container A (b) the same as that of container A (c) half that of container A (d) impossible to determine (ii) From the same choices, describe the internal energy of the gas in container B.
A sealed cubical container 20.0 cm on a side contains a gas with three times Avogadros number of neon atoms at a temperature of 20.0C. (a) Find the internal energy of the gas. (b) Find the total translational kinetic energy of the gas. (c) Calculate the average kinetic energy per atom, (d) Use Equation 10.13 to calculate the gas pressure. (e) Calculate the gas pressure using the ideal gas law (Eq. 10.8).
A sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P21.65). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state, (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally, (f) Find Q, W, and Eint for each of the processes, (g) For the whole cycle A B C A, find Q, W, and Eint.
Which of the assumptions below is not made in the kinetic theory of gases? (a) The number of molecules is very large. (b) The molecules obey Newtons laws of motion. (c) The forces between molecules are long range. (d) The gas is a pure substance. (e) The average separation between molecules is large compared to their dimensions. (f) of (his account are correct statements necessary for a clear and complete explanation? (ii) Which are correct statements that are not necessary to account for the higher thermometer reading? (iii) Which are incorrect statements?