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(a) Consider that 25.0 g of CH4(g) is contained in a sealed 2.0-L container at 30°C. What would be the pressure if the gas were: (i) Acting as an ideal gas? (ii) Acting as a van der Waals gas? (iii) Obeying the virial equation but only when the first two terms are significant? (at 30°C, B for CH4(g) = -43.9 cm³.mol-¹)

(a) Consider that 25.0 g of CH4(g) is contained in a sealed 2.0-L container at 30°C. What would be the pressure if the gas were: (i) Acting as an ideal gas? (ii) Acting as a van der Waals gas? (iii) Obeying the virial equation but only when the first two terms are significant? (at 30°C, B for CH4(g) = -43.9 cm³.mol-¹)

General Chemistry - Standalone book (MindTap Course List)
General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Chapter5: The Gaseous State
Section: Chapter Questions
Problem 5.145QP: A 275-mL sample of CO gas is collected over water at 31C and 755 mmHg. If the temperature of the gas...
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Question 1 (a) Consider that 25.0 g of CH4(g) is contained in a sealed 2.0-L container at 30°C. What would be the pressure if the gas were: (i) Acting as an ideal gas? (ii) Acting as a van der Waals gas? (iii) Obeying the virial equation but only when the first two terms are significant? (at 30°C, B for CH4(g) = -43.9 cm³.mol-¹) (b) If the volume of the gas was compressed isothermally to 200 mL at T = 30°C, what would the pressure in (i), (ii), and (iii) become?
Transcribed Image Text:Question 1 (a) Consider that 25.0 g of CH4(g) is contained in a sealed 2.0-L container at 30°C. What would be the pressure if the gas were: (i) Acting as an ideal gas? (ii) Acting as a van der Waals gas? (iii) Obeying the virial equation but only when the first two terms are significant? (at 30°C, B for CH4(g) = -43.9 cm³.mol-¹) (b) If the volume of the gas was compressed isothermally to 200 mL at T = 30°C, what would the pressure in (i), (ii), and (iii) become?
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