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Organic Chemistry of Metabolic Pathways
Metabolic pathways allude to the arrangement of chemical catalyzed reactions that lead to the transformation of a substance into the final product. Metabolic pathways incorporate a progression of reaction where the substrate is changed continuously and the transitional metabolites are persistently recovered.
Glucogenesis
Glucogenesis is a metabolic pathway in which glucose is produced from carbon substrates that are not carbohydrates. This process is observed in plants, animals, fungi, bacteria and other micro organisms. The general definition for glucogenesis or gluconeogenesis is as follows,
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- e (ii) (iii) MeO Me. TSN CO₂Et CI CI PCY₁ Ru PCy, Ph benzene, A (cat.) Coz(CO), (cat.) CO, A AD-mix a: K₂OsO₂(OH)4 (cat.) (DHQ)2-PHAL (cat.) K,Fe(CN)6. K₂CO, -BuOH/H₂O, 1:1 TsN Me- MeO OH CO₂Et OHHO Hoor OH CF3 Br Br Ac₂O, pyr, DMAP COOH Bpin N3 cal Fe(OAc)2/ligand CN BnNH₂ Pd₂(dba)3 SPhos K3PO4 Cul, K₂CO3 cat. [Ir(cod)Cl]2 CI, MeOBIPHEP 3,4-(NO₂)BZOH CS₂CO3Express the equilibrium constant for the following reaction: 2 CH2CI2 (g) + Cl2 (g) =2 CHCI3 + H2 (g) [CHCI3]CH2] k = %3D [CHCI3]°[H2] k = %3D [CHCI,ICI,] [CHCI;]*tC!,] [CHCI;]°[H;] %3D [CHCI,ICI,] k%3D [CHCI;][H2] %3D [CHCI3][H2] k%3D [CHCI2[CI]
- 2. In a laboratory experiment you react 20.0 mL of 25% by mass C2H&N2 with 8.000 NiCl2.6H20 to obtain the product Ni(NH2CH2CH½NH2j3Cl2 complex. The C2H3N2 solution used in this experiment is 25.0% by mass, with a density (d) of 0.950 g/mL. (MW NICI2.6H2O= 237.69 g/mole, MW C2HgN2=60.10 g/mole, MW tris(ethylenediamine)nickel(II)chloride = 309.89 g/mole) a. Write down the balanced equation of the synthesis. b. Determine the number of moles of each reactant that you use. c. Determine which reactant is the limiting reactant, giving your reasoning. Show all your work to get full credit. (5 points) d. Calculate your percent yield if the dry product weighs 7.000 g.09:29 What is the geometry for the [Cr(H20)4CI2] compound? (4) OA. Square planar O B. Tetrahedral OC. Trigonal planar O D. Octahedral Add a caption... > Status (Custom)Find Ecell = 0.48V. Use dhis regult along with the equilibrium conlentretion of Lu“ (mol/L) wheun 24. C[Cu (NH3), ) = 0.10 mol /L and [N H3] = 6.1 mol/h to calceulate the cqnillibriem Lonstant for the formation of [cu(NH3),]"]
- Classify each of the coordination compounds according to the coordination number. O Macmillan Learning → 2 BalFeBr [Fe(CO),] The oxidation state is 3 K, (CoF [G(CO) ] Answer Bank [Ag(CN), for the central metal atom in [Hgl₂]. (CoC), |CaCigh 6 (Hgl,Nernst equation for pair CIO4|Cr': RT E = E° + nF In «(CIO, )a*(H*) a(Cl¯) RT E = E° + nF Cloa(CIO; )a(H*) a(Cl¯) RT a(CIO, Ja*(H*) E = E° – -In nF a(Cl¯) nF a(CIO, )a*(H*) E = E° + lg RT a(Cl¯)Potentially Useful Information Spectrochemical Series: | < Br < SCN < Cl° < NO3¯< F° < OH° < C2O4²- ~ H2O < NCS < NH3 < en < PPH3 A student synthesizes and isolates the following coordination compound [Ni(H2NCH2CH2NH2)3]Cl2 (molar mass = 309.8966 g/mol) according to the balanced reaction below. In the experiment, the student reacts 2.500 g of nickel (II) chloride hexahydrate (molar mass = 237.6878 g/mol) with 4.000 g of ethylenediamine (molar mass = 60.0992 g/mol). After isolating the product, the student collects 3.200 g of the nickel coordination compound. NICI2•6H2O (aq) + 3H2NCH2CH2NH2 (1) → [Ni(H2NCH2CH2NH2)3]Cl2 (s) + 6H2O (1) Given the transition metal compound, Na4[Co(C204) (CN)4], what is the oxidation state of cobalt, as well as the coordination number of cobalt in this compound? This compound is soluble in water. The oxidation state of cobalt is Cobalt has a coordination number of Your answer should be an integer.
- Potentially Useful Information Spectrochemical Series: | < Br < SCN < Cl° < NO3¯< F° < OH° < C2O4²- ~ H2O < NCS < NH3 < en < PPH3 A student synthesizes and isolates the following coordination compound [Ni(H2NCH2CH2NH2)3]Cl2 (molar mass = 309.8966 g/mol) according to the balanced reaction below. In the experiment, the student reacts 2.500 g of nickel (II) chloride hexahydrate (molar mass = 237.6878 g/mol) with 4.000 g of ethylenediamine (molar mass = 60.0992 g/mol). After isolating the product, the student collects 3.200 g of the nickel coordination compound. NICI2•6H2O (aq) + 3H2NCH2CH2NH2 (1) → [Ni(H2NCH2CH2NH2)3]Cl2 (s) + 6H2O (1) What is the limiting reactant in the reaction above? In this reaction, the limiting reactant is... O ethylenediamine O nickel (II) chloride hexahydrate O This reaction is stoichiometric, so there is no limiting reactant.+2 a. Ag (ac) + 2NH3 (ac)Ag (NH)2 (ac) + Cl ac) b. AgCl(s) + Agiac) c. Ni(CO) 4 (0) Ni (s) +4CO(0) d. CH3 COOH (ac) + C2H5OH (ac) CH3 COOC,H5 (ac) + H20m [CH3COOC,H5] [H20] O una. K(ea) %3D [CH;COOH] [C,H5 OH] O b. K(ea) [Ni(CO) 4] OC. [CH3COOC, H5] Krea) %D [CH3COOH] [C2H5OH] O d. Kreg) = [Ag*][CI]eston 2 The complex (C u(NH,,"bb byht with a wamlength of 1,,1abserbs hight is the valus of A n K3 mele? 342 nm.What