A chemist needs to create a series of standard Cu²+ (aq) solutions for an absorbance experiment. For the first standard, he uses a pipet to transfer 25.00 mL of a 2.49 M Cu²+ (aq) stock solution to a 250.0 mL volumetric flask, and he adds enough water to dilute to the mark. He then uses a second pipet to transfer 10.00 mL of that solution to a 50.00 mL volumetric flask, and he adds enough water to dilute to the mark. Calculate the concentration of the Cu²+ (aq) solution in the 50.00 mL. volumetric flask. concentration: M

A chemist needs to create a series of standard Cu²+ (aq) solutions for an absorbance experiment. For the first standard, he uses a pipet to transfer 25.00 mL of a 2.49 M Cu²+ (aq) stock solution to a 250.0 mL volumetric flask, and he adds enough water to dilute to the mark. He then uses a second pipet to transfer 10.00 mL of that solution to a 50.00 mL volumetric flask, and he adds enough water to dilute to the mark. Calculate the concentration of the Cu²+ (aq) solution in the 50.00 mL. volumetric flask. concentration: M

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter6: Types Of Chemical Reactions And Solution Stoichiometry

Section: Chapter Questions

Problem 43E

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An artificial fruit beverage contains 12.0 g of tartaric acid, H2C4H4O6, to achieve tartness. It is titrated with a basic solution that has a density of 1.045 g/cm3 and contains 5.00 mass percent KOH. What volume of the basic solution is required? (One mole of tartaric acid reacts with two moles of hydroxide ion.)
1. Calcium in a sample solution is determined by atomic absorption spectroscopy (AAS). A stock solution of calcium is prepared by dissolving 1.834 g CaCl, 2H,0 in water and diluting to 1 litre. From this stock solution, the second stock solution is prepared by the dilution factor of 10. Three standard solutions of calcium are prepared from the second stock solution with the following dilution factor: 20 (first standard solution), 10 (second standard solution) and 5 (third standard solution). A blank solution is prepared as well. Absorbance signals of AAS are as follows: 1.5 (blank solution), 10.6 (first standard solution), 20.1 (second standard solution), 38.5 (third standard solution), 29.6 (sample solution). (Molar mass; Ca = 40.00 g mol-, CI = 35.45 g mol-, 0 = 16.00 g mol-', H = 1.00 g mol-1) a. Construct ONE (1) plot that could be used to represent the calibration curve. b. From the plot of Q1a, determine the amount of calcium in parts per million.
Exactly 10.00-mL aliquots of a solution containing phenobarbital were measured into 50.00-mL volumetric flasks and made basic with KOH. The following volumes of a standard solution of phenobarbital containing 2.000μg/mL of phenobarbital were then introduced into each flask and the mixture was diluted to volume: 0.000, 0.500, 1.00, 1.50, 2.00 mL. The fluorescence of each of these solutions was measured with a fluorimeter, which gave values of 3.26, 4.80, 6.41, 8.02, 9.56, respectively. a. plot the data. b. derive a least squares equation for the data plotted in (a). c. find the concentration of phenobarbital from the equation in (b). d. calculate a standard deviation for the concentration obtained in (c).
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