A chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 18.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. 6C, (e) + 2Fe,0, (s) 4FeC1, () + 30, (e) 200, (e) + 4H₂O(e)- 2CH, OH (e) + 30, (e) All 50 kJ AS 172 AG=J AH Which is spontaneous? O this reaction O the reverse reaction O neither } AS= -0 K 1353. kJ AG = 4, KJ Which is spontaneous? O this reaction O the reverse reaction Oneither 05 d X Lara G dh 4

Chemistry & Chemical Reactivity
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Chapter18: Principles Of Chemical Reactivity: Entropy And Free Energy
Section18.7: The Interplay Of Kinetics And Thermodynamics
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ity and... 18.3 Gibbs Free E... 5.3 Enthalpies of...
ENTROPY AND FREE ENERGY
Calculating dG from dH and dS
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A chemical engineer is studying the two reactions shown in the table below.
In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 18.0 °C and constant total pressure.
Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the
second reaction. The results of her measurements are shown in the table.
Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under
the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous
because the system is at equilibrium.
B
X
6C1, (e) + 2Fe,0, (s) 4FeCl, (s) + 30₂(e)
Explanation
2C0₂(e) + 4H₂O(e)- 2CH, OH (e) + 30, (e)
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Transcribed Image Text:ity and... 18.3 Gibbs Free E... 5.3 Enthalpies of... ENTROPY AND FREE ENERGY Calculating dG from dH and dS ! 4 N 20.532 @ 2 W S A chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 18.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. B X 6C1, (e) + 2Fe,0, (s) 4FeCl, (s) + 30₂(e) Explanation 2C0₂(e) + 4H₂O(e)- 2CH, OH (e) + 30, (e) #3 E D Check 27 C 8P3JH-VIqeviKFP6W0cqJcWJdIACROQwyw24GWHIn2UZOXOs6vIP4nC7cNRhg_zK4Zgz8... Q 18.5 Gibbs Free E... Reading Schedule 19.6 Reduction Po....a SOLUTION: The le... Math 115 W-S Fall.... $ 4 R F % 5 V AH= 50. kl AS 172 AG=kJ Which is spontaneous? O this reaction O the reverse reaction O neither AH AS = -0 AG = 4, KJ 1353, kl I J K Which is spontaneous? O this reaction O the reverse reaction O neither T tv S G < 6 Y MacBook Pro B X Is TV A & 7 H 3 Ⓒ2022 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Accessibility Oa U N #CO The 8 J 1 ( 9 M 05 ( Q K O ) .0 0 L Lara V * - P dh H TR 4) command
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