A buffer solution consists of 0,25 mol∙dm–3 acetic acid (HC2H3O2; Ka= 1,8 x 10–5) and 0,35 mol∙dm–3 potassium acetate (KC2H3O2). Calculate the pH of the buffer solution. A small quantity (0,050 mol) of solid KOH is added to 1 dm3 of the buffer. This quantity is so small that it does not affect the volume of the buffer. Calculate the new pH of the buffer solution after the KOH has been added.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter17: Principles Of Chemical Reactivity: Other Aspects Of Aqueous Equilibria
Section: Chapter Questions
Problem 89GQ: A buffer solution is prepared by dissolving 1.50 g each of benzoic acid, C6H5CO2H, and sodium...
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A buffer solution consists of 0,25 mol∙dm–3 acetic acid (HC2H3O2; Ka= 1,8 x 10–5) and 0,35 mol∙dm–3 potassium acetate (KC2H3O2).

  1. Calculate the pH of the buffer solution.
  2. A small quantity (0,050 mol) of solid KOH is added to 1 dm3 of the buffer. This quantity is so small that it does not affect the volume of the buffer. Calculate the new pH of the buffer solution after the KOH has been added.
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