9. The equation of the straight line determined from a least squares fit procedure for an experiment in which the instrument readout, R, was plotted on the y-axis and the concentration, C, in parts per million was plotted on the x- axis is R = 1.37 C + 0.029 What is the analyte concentration in the unknown if the instrument readout for the unknown is 0.481?
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- 1-arr In a study of the gas phase decomposition of phosphine at 120 °C PH3(g)- →1/4 P4(g) + 3/2 H2(g) the concentration of PH3 was followed as a function of time. It was found that a graph of In[PH3] versus time in seconds gave a straight line with a slope of -2.50×10² s1 and a y-intercept of -3.24. Based on this plot, the reaction i v O order in PH, and the half life for the reaction is seconds. zero first secondWas the gradual color change observed when the sodium thiosulfate (Na2S2O3) crystal was added to the aqueous solution of KI/12 in Station Cevidence of a chemical or physical change?What are the differences between systematic and random errors and how do they effect accuracy and precision? In what circumstances would you use standard addition (versus a normal calibration curve) to determine the amount of an analyte in a sample? A urine sample, containing analyte Z is analysed by the standard addition method where 5 mL of the original sample was mixed with increasing amounts of a Z standard and each solution diluted to a volume of 50 mL prior to analysis. A plot of the final concentration of the standard in each of the 50 mL samples (x axis) versus The measured signal from the analysis of each 50 mL sample (on y axis) produced a straight line with the general equation: y = 44.72x + 4.06 what was the final concentration of Z in the 50 mL standard addition sample? what was the initial concentration of Z in the original urine sample?
- In the Analytical Chemistry laboratory, one of the B.Sc student Ms. Fatma wanted to analyze the presence of Iron(II) ion in the water samples collected from Sohar Industrial Area in the Sultanate of Oman and analyzed by Spectrophotometric method. (1) 250.00 mL of this water sample (Solution A) known to contain unknown amount of FeSO4. She has diluted Solution A by a dilution factor 10 to make 250.00 mL solution, which she labeled Solution B. Using Spectrophotometer, she has measured the absorbance value (0.642) for Solution B at 508 nm using 1.00 cm cell (cuvet). The molar absorptivity value for Fe2* ion at 508 nm is ɛ508 = 30.8 M-1cm1. (i) What volume of the solution A did she require to make the 250.00 mL of Solution В? (ii) in (i)? What instrument should she use to transfer the volume of the Solution A calculated (ii) Concentration of FeSO4 in Solution B. (iv) Concentration of FeSO4 in Solution A. Mass of FeSO4 in Solution A (Show your calculation) (v)Suppose a difference in changes in plasma oxytocin levels between two groups of 0.2 pg/mL would be of interest to researchers and that changes within each group have standard deviation o = 0.1 pg/mL. The power of a one-sided two-sample t-test to detect a difference in changes in oxytocin levels of 0.2 pg/mL between two groups of 5 women at the 5% level isA new analytic instrument is capable of detecting picogram quantities of a chemi-cal substance. How many times more capable is this instrument than one that candetect nanogram quantities of the same chemical?
- A clinical chemist obtained the following data for the alcohol content of a sample of blood: % C2H5OH: 0.084, 0.089, and 0.079. Calculate the 95% confidence interval for the mean assuming that (a) the three results obtained are the only indication of the precision of the method and that (b), from previous experience on hundreds of samples, we know that the standard deviation of the method s 5 0.005% C2H5OH and is a good estimate of s.A solution was prepared from an amount n = (0.500 ± 0.005) mol dissolved in a volume V = (250.0 ± 0.5) cm3. What is the absolute uncertainty in the concentration in units of mol dm-3?(b) Shown below are three different van Deemter curves for particles of varying sizes. Propose explanations for their differences based on terms in the van Deemter equation. Thereby explaining why smaller particle size is desirable. HETP (μm) 60 9 20 0 0 2 10 5 µm 4 FLOW RATE (mL/min) 6 10 μm 3 μm 8
- Sample IdentificationCodeConcentration of M%TA=2-log(%T)Q50004.00 x 10-417.90.75Q50013.20 x 10-425.00.6Q50022.40 x 10-435.70.46Q50031.60 x 10-450.20.3Q50048.000 x 10-570.80.15SampleIdentificationCode%TA=2-log(%T)AMQ0210150143.70.359518560.360.000192Q0210150244.10.355561410.360.00018Q0210150343.80.358525890.360.00017Q0210150444.10.355561410.360.00018Q0210150543.80.358525890.360.00017What was their percent error?43%Does Batch 021015 meet legal requirements?No, because it is not between 2.85 * 10(4) and 3.15 * 10(4)Well #DropsBluedye1234567891012345678910Drops 9Distilled water876543210Concne 0.26tration0.52Test Tube #0.781.041.3Solutions3Concentration (M)2.082.32.6Concentration (ppm)1:1 dilution11.82Starting Dilution21.562:1 dilution0A.Zero standard0Was your calibration curve as linear as you expected?B.Did you experience any âdriftâ of the resistance readings?C.What is the equation of your best-fit line?D.What commercial drink did you analyze?E.Assuming…List and define the indicators that are used to assess the performance of a specific analytical method under specified conditions.In a volumetric determination of an analyte A, the data obtained and their standard deviations are as follows: Initial buret reading 0.19 mL 0.02 mL Final buret reading 7.86 mL 0.03 mL Sample mass 63.0 mg 0.2 mg From the data, find the coefficient of variation of the final result for the %A that is obtained by using the equation that follows and assuming there is no uncertainty in the equivalent mass. %A= titrant volume x equivalent mass x 100 %/ sample mass Coefficient of variation = Submit Answer % Try Another Version 10 item attempts remaining