help??? 9. How might you carry out the following selective transformations? Use the letters from the table to indicate yourchoice of reagents.1. excess NaBH4Dess-Martina.d.aqueous HCIg.HOCH2CH2OH / HCI2. H3O+periodinane1. 1eq NaBH41. Li(CH3)2Cu(CH3)3SICI /b.e.h.2. H3O+2. H3O+(CH3CH2)3N1. CH3MgBr/dry1. LiAlH4C.f.etheri.KMnO4. H3O+2. H3O+2. H3O+a.b.SHHO CH3C.d.OH앳요.°요요HHOH

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Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter8: Addition Via Carbocation

Section: Chapter Questions

Problem 37CTQ

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6. Identify the best reagent(s) for this reaction. (see attached screenshot). a. H2SO4, HgSO4, H2O b. 1. Disiamylborane, 2. HO–, H2O2 c. K2Cr2O7, H+ d. NaOCl e. H2, Pd
Match the drugs with the corresponding Phase 1 reaction that will happen appropriately with the highligthed portion of the drug. A: C4 of Benzene ring B: Methyl group of Nitrogen C: -NH-NH2 moiety D: N,N-dimethyl moiety E: Ring S CHOICES: A. Desulfuration B. Aromatic hydroxylation C. Hydrazo reduction D. Nitro reduction E. Sulfur oxidation F. Deamination G. N-demethylation
Explain the features of E1 reactions are worthy of note ?
1. Which of the following is the strongest nucleophile? Refer to the diagram below with an MeOH, MeSH, etc. 2. Which of the following is true about the stereochemistry of SN1 reaction?a.retention of configuration at the electrophilic centerb.50:50 mixture of retention and inversion of configuration at the electrophilic centerc.inversion of configuration at the electrophilic centerd. slightly more inversion than retention at the electrophilic center
select the most appropriate reagent(s) to effect the change. K2Cr2O7, H+ H2, Pd 1. Disiamylborane, 2. HO–, H2O, H2O2 NaOCl H2SO4, HgSO4
Which compound is not a possible product in the reaction below ( F2 is in excess F2and UV light the catalyst).CHA + F2 -->O CFAO CHFaO CHF-O CH2F2O CHaF
please quickly thanks ! 3.Please write out the major reaction and side-reaction in the preparation of ter-butyl.chloride, and write out the key points to use separation funnel in this process.
9. Product of the reaction of nitrobenzene with sulfuric acid in the presence of oleum at 60 °C:a) o-nitro benzenesulfonic acidb) m-nitro benzenesulfonic acidc) p-nitro benzenesulfonic acidd) None of the above 10. Due to their ability to move through ducts or pipes, they are generally called fluids:a) Solidsb) Solid mixturesc) Gasesd) Liquids and gases
For butenafine, develop a synthesis that starts with napthalene and benzene. (aromatic methyl groups can be converted to alkyl bromides using Br2/light, and aldehydes by heating the alkyl bromide in DMSO, eg. ArCH3 to ArCH2Br then to ArCHO).
Show the difference between SN1 and E1 Reactions ?
1.Show the Elimination reaction of 2-bromopentane. 2.What contributed to formation of minor and major product?
Show the relationship between E2 Reactions and Alkyne Synthesis ?

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