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- List the following order of increasing reactivity in an SN1 reactionb) Explain in detail what characteristics of the alkyl halide influence whether a mechanism will be SN1 or SN2. c) Explain in detail what characteristics of a nucleophile influence whether a reaction will be SN1 or SN2.What is the slow (rate-determining) step in any electrophilic aromatic substitution reaction? Please provide a detailed explanation.
- Rank these in order of increasing reactivity in an SN1 reactionWhat is the best way to remeber the differences between Sn1, Sn2, E1 and E2 reations?For SN1 Explain the order in which 2o (secondary) alkyl halides reacted (fastest to slowest) and explain why. 2o (secondary) compounds listed are: (see picture) 2-chlorobutane 2-bromobutane bromobenzene bromocyclopentane bromocyclohexane Base your explanations on the following considerations: the nature of leaving group, the effect of structure, steric hindrance and any other feature. Be sure to explain which alkyl halides did not react and why
- For SN1 Explain if 3o ( tertiary) alkyl halides reacted (fastest or slowest) explain why. Be sure to explain if alkyl halides did not react or did react and why. 3o (tertiary) compounds listed are: 2-chloro-2-methylpropane (see picture) Base your explanations on the following considerations: the nature of leaving group, the effect of structure, steric hindrance and any other feature.Q10. For each of the following reactions (a-b), predict whether the substitution is more likely to occur following an Sn1 or Sn2 mechanism; explain your reasoning. Draw the products of each nucleophilic substitution paying particular attention to the stereochemistry of carbon 1. a) Br, CH3 MeOH H3C b) Br NaOH 1 DMF* H3C *N,N-dimethylformamideOrder each of the following sets of compounds with respect to SN1 reactivity.
- Provide a reasonable mechanism for the following reaction. TMSO SnCl4 OMe Meo OMeHow do you properly write an SN1 reaction, with transition states/intermediate steps included?Under second-order conditions (strong base/nucleophile), SN2 and E2 reactions may occur simultaneously and compete witheach other. Show what products might be expected from the reaction of 2-bromo-3-methylbutane (a moderately hindered 2°alkyl halide) with sodium ethoxide.