5. Predict the ESR spectrum of pentafluorooxovanadium(IV), VOF, . For v, I=7/2 withexplanation.6. Show how an ESR spectrum having three lines could arise by (a) hyperfine coupling to twonuclei with spin I= ½ and (b) hyperfine coupling to a nuclear spin 1. How can these twopossibilities be distinguished?

Answered: Image /qna-images/answer/af1d7dca-e41e-4917-9aea-567aad6e9764.jpg

Answered: 5. Predict the ESR spectrum of…

Science

Chemistry

5. Predict the ESR spectrum of pentafluorooxovanadium(IV), VOF,. For $v, I=7/2 with explanation.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter15: Introduction To Electronic Spectroscopy And Structure

Section: Chapter Questions

Problem 15.56E

See similar textbooks

Related questions

Q: Which of the following aqueous solutions are good buffer systems? O 0.33 M ammonia + 0.39 M sodium…

Q: Draw the structure of the amino acid L-leucine at each pH: (a) 6; (b) 10; (c) 2. Which form…

Q: An oxide of nitrogen was found by elemental analysis to contain 30.4% nitrogen and 69.6% oxygen. If…

A: Calculate empirical formula and molecular formula....

Q: 13.25 Use the Nernst equation to calculate the cell potentials of the following cells at 298 K. (a)…

Q: A solution is 0.085 M potassium carbonate, K2CO3. Determine the pH of the solution and the…

A: Since you have asked multiple questions, we will solve the first question for you. If you want any…

Q: 2. Determine the molecular weight (molar mass) of gases at STP which have densities C a. 0.090 g/L…

A: At STP -> T = 273 K P = 1 atm

Q: Rank the relative rates of the following alkyl halides in an E1 reaction.

A: Elimination reaction of alkyl halide: Alkyl halide gives an elimination reaction by reacting with a…

Q: For the chemical reection A-B.Ce plot of JAk versus time is found to give a straight ne with a…

A: We would write integrated rate law for different orders and straight line graphs for different order…

Q: 26. Given the following reaction, what volume of oxygen would be needed to react with 250. grams of…

A: Moles of propane = 250 g / 44.1 g mol-1 =5.6689 mol 1 mol of propane = 5 mol of O2 5.6689 mol…

Q: 13.71 In a copper plating experiment in which copper metal is deposited from a copper(II) ion…

Q: The reaction C(s) + 2H, (g) = CH,(g) has K, - 0.263 at 1000. K. Calculate he total pressure at…

A: Dalton's law states that total pressure of mixture of gases is equal to the sum of the partial…

Q: For the reaction PCI3(g) + Cl2(g) S PCI5(g) at a particular temperature, Kc = 24.3. Suppose a system…

Q: A solution with 3 g of potassium chloride (KCl) in 100 g of water is prepared. Calculate the percent…

A: Since you have asked multiple questions, we will solve the first question for you. If you want any…

Q: Which of the following phase diagrams corresponds to a system wherein boiling occurs before the two…

A: The phase diagram corresponds to a system where boiling occurs before the two liquids are Fully…

Q: This picture shows A) an insoluble ionic solid B) a partially soluble ionic compound C) a fully…

A: A compound is said to be soluble if it is distributed homogeneously when it is dissolved in a…

Q: A chemistry student weighs out 0.261 g of citric acid (H,C,H,O,), a triprotic acid, into a 250. mL…

A: Given-> Weight of citric acid = 0.261 gm Volume of citric acid = 250 ml Molarity of NaOH =…

Q: Saved A reaction is experimentally found to follow the rate law, Rate k[A] where k = 0.355 Mmin.…

Q: If 55.3 mL of 0.75M copper sulfate is used to create malachite with excess sodium bicarbonate,…

A: Firat we would write a chemical reaction to copper hydroxide and sodium bicarbonate to give…

Q: Consider the reaction. %23 H :Br: CH3 Н— Br: H -C C -CH3 + H H H H Add curved arrows for the first…

A: Note : 1-Propene reacts with proton produces the carbocation and bromine anion. (see below).

Q: Considering perfect gases, which state function is zero when two substances are mixed?…

Q: Balance the following reactions below using the change in oxidation number method. 1. PЬО, + НBr —…

Q: 22. A 0.716 mole sample of gas is kept under 875 torr pressure and occupies 6.0 L of space. What…

Q: A student has calibrated his/her calorimeter and finds the heat capacity to be 14.8 J/°C. S/he then…

Q: Complete and balance the following equation: S(s)+HNO3(aq)→H2SO3(aq)+N2O(g) (acidic solution)…

A: Given, The balancing equation is: S(s)+HNO3(aq)→H2SO3(aq)+N2O(g) (acidic solution)

Q: Unbalanced Reaction Equation: Fe2+(aq) + MnO4-(aq) → Fe3+(aq) + Mn2+(aq) Question Content Area…

A: We have given the unbalanced reaction equation: Fe2+(aq) + MnO4-(aq) → Fe3+(aq) + Mn2+(aq)

Q: Estimate the freezing point of 250 cm3 water sweetened by the addition of 2.7 g sucrose. Treat the…

Q: 7. Calculate the weight of 20.0 liters SO2 at STP.

Q: Liquid mercury has a density of 13.69 g cm-3, and solid mercury has a density of 14.690 g cm-3 both…

A: Given that, at -38.87°C and 1 bar pressure, The density of liquid mercury is dl = 13.69 g/cm3. The…

Q: A sample of methane experiences a temperature change of -92.79 °C while releasing 487.4 joules of…

Q: When the following reaction is ot equilbrium, which of these relationships is always true? 2 Ogig) -…

A: Answer: Given balanced chemical equation is shown below: 2O3(g)↔3O2(g) It means, 2 mole ozone is…

Q: A reaction has AS >0 and AH> 0. Which statement about this reaction must be correct? (A) If carried…

A: Answer: This question is based on the basic prediction about a reaction when it is an endothermic…

Q: Write the balanced NET ionic equation for the reaction when Li,sO, and Ca(NO,), are mixed in aqueous…

A: We would solubility rules to predict the products formed when given compounds are mixed.

Q: e e Inert Inert Electrode Na(l) Electrode Cl2(9) Molten NaCI CI- Na+ Anode Cathode

Q: 23. What volume of carbon dioxide gas at STP could be produced from the decomposition of 150.0 grams…

A: ★ Answer : 33.55 Litres CO2 gas will be produced at STP from the decomposition of 150g CaCO3. ★…

Q: What is the molecular formula of each compound?

A: Molecular formula: In a molecular formula we describe the number of atoms of all the elements…

Q: Please write out all the formulas and steps: Known: 5 % NaOCI: Molar mass of = 165.15 g/mol Quantity…

A: To find : Number of moles of NaOCl, number of moles of NaOH, and theoretical yield of…

Q: The PH of 50 ml 0.1 mol/ L acetic acid is 4.8 when 50% titrated with 0.5 mol/L sodium hydroxide.…

A: When acetic acid is titrated with NaOH, following reaction occurs within the reaction mixture.…

Q: R `OOH

Q: In a two-vessel technique titration set-up, what is the unknown substance if the volume of…

A: phenolphthalein and bromocresol can be used in determination of alkalinity of water The alkalinity…

Q: What is the maximum wavelength of light capable of removing an electron from a hydrogen atom in the…

A: Maximum wavelength means minimum energy...

Q: Gitenqueteophite indicate which, the Stronger muctee, ethoxide of ethomat Explain Joo fa both of.

Q: Using net ionic equations and solution stoichiometry, calculate the molarity of the principal…

A: net ionic equation is- CH3COO- + H+→CH3COOH (aq) Also, Moles = Molarity * Volume

Q: Suppose for a synthesis of hydrogen fluoride from hydrogen and fluorine, 3.000 moles of H2 and 6.000…

A: The equilibrium reaction given is, => H2 (g) + F2 (g) ↔ 2 HF (g) Kc =…

Q: Determine (a) the rate equation and (b) the rate constant for the hypothetical reaction A+ B → C…

A: Let order with respect to A is x and order with respect to B is y

Q: Target NO:(g) + H2(8) = NO(g) + H2O(g) Reaction A 2NO2(g) = 2NO(g) + O2(g) Ke = 1.45 x 10-6 at 500 K…

A: Kc is the ratio of the equilibrium concentrations of product over equilibrium concentrations of…

Q: He+ Al → n+ 2 13 01:23:26 Multiple Choice 16 31 14 to 15 3 14 30 15 Next> 20 of 35

Q: 3

Q: At 400°C, Ke = 64 for the equilibrium H2(g) + 12l9) = 2HI(g). If 3.00 mol H2 and 3.00 mol I2 are…

Q: 6. Prove that the Is and 2p, orbitals for the H atom are orthogonal. [Remember: when checking if two…

A: Here we are required to show that two wavefunction of hydrogen atom are orthogonal to each other

Q: Saved A city's water supply is contaminated with a toxin at a concentration of 0.63 mg/L. For the…

A: Given-> Initial concentration of toxin = 0.63 mg/L Final concentration of toxin=1.5 ×…

Question

5. Predict the ESR spectrum of pentafluorooxovanadium(IV), VOF, . For v, I=7/2 with
explanation.
6. Show how an ESR spectrum having three lines could arise by (a) hyperfine coupling to two
nuclei with spin I= ½ and (b) hyperfine coupling to a nuclear spin 1. How can these two
possibilities be distinguished?

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Step by step

Solved in 3 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Discuss how the Fermi contact interaction and the polarization mechanism contribute to spin-spin couplings in NMR.
Vibrational wavenumbers for K[N3] are 2041, 1344 and 645 cm-1. Draw the structure of the [N3]- ion and sketch the 3 vibrational modes. Which are IR active?
5. For a d7 complex, write all possible spin-allowed transitions, including the ground state and excited state molecular term symbols involved and approximate E/B values for: (i) Aoct/B = 10; (ii) Aoct/B = 30.
(d) By considering a nuclear spin I = 3/2 of a potassium 3°K atom, obtain all possible hyperfine states F. Together with all the fine states, j, you obtained in (a), draw all the fine and hyperfine level splitting together.
4. It is given the ratio is at A/B=24.00 a Tanabe-Sugano diagram for a d' system. Please answer the following questions. a) Write all transitions b) Determine spin-allowed transitions c) Calculate the value of B and A for the Cr3+ ion in [Cr(H2O)6)]³+ if v1=17000 cm-1, v2=24000 cm-1 and v3=37000 cm-!.
The inorganic complex OsCl3(CO); can exist as either a fac-or mer-isome Calculate the number of infrared and Raman active C-O stretching vibration for both isomers and determine if it is possible to distinguish between the fac and mer- isomers using both infrared and Raman spectroscopy.
2. A combined system is formed from two separate systems of N localized atoms of spin-1/2 each. While the two systems remain separate (a) Find the number of configurations which give a total spin excess S = S, +S, where S, and S, are the excess spins of the separate systems. (b) For what values of S, and S, is this number of configurations maximum?
It might be unexpected that the Karplus equation, which was first derived for 3JHH coupling constants, should also apply to three-bond coupling between the nuclei of metallic elements such as tin. T.N. Mitchell and B. Kowall (Magn. Reson. Chem. 33, 325 (1995)) have studied the relation between 3JHH and 3JSnSn in compounds of the type Me3SnCH2CHRSnMe3 and find that 3JSnSn = 78.86 Hz and 3JHH =27.84 Hz. (a) Does this result support a Karplus type equation for tin nuclei? Explain your reasoning. (b) Obtain the Karplus equation for 3JSnSn and plot it as a function of the dihedral angle. (c) Draw the preferred conformation.
Predict 31PNMR spectrum of cis-[Pt(PR3)2Cl2]. Given that phosphorus-31 (100% abundant), platinum-95 (33% abundant), all have a nuclear spin quantum numbers of (I = ½)
What are the conditions for a molecule to be Raman active, IR active.
Calculate the Magnetic susceptibility of [Cr(L)]Cl₂.2H₂O? where for an A ground state a= 4, and for an E ground state, a= 2
Explain 1H NMR: Spin-Spin Splitting ?