4. What organometallic and carbonyl compound could be used to prepare the following Propose two different carbonyl starting materials and corresponding compound? organometallic reagents. OH sa OCH3
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- C. How would you synthesize the given target compound in multistep syntheses? 2 НО CO₂H CH3A step in a synthesis of PGE1 (prostaglandin E1, alprostadil) is the reaction of a trisubstituted cyclohexene with bromine to form a bromolactone. Propose a mechanism for formation of this bromolactone and account for the observed stereochemistry of each substituent on the cyclohexane ring. Alprostadil is used as a temporary therapy for infants born with congenital heart defects that restrict pulmonary blood flow. It brings about dilation of the ductus arteriosus, which in turn increases blood flow in the lungs and blood oxygenation.Melamine, used as a fire retardant and a component of the writing surface of white boards, can be prepared from s-trichlorotriazine through a series of SNAr reactions with ammonia. The first substitution takes place rapidly at room temperature. The second substitution takes place near 100 °C, and the third substitution requires even higher temperature and pressure. Provide an explanation fatr this reactivity.
- The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold Helminthosporium sativum, involves the following base treatment of a keto tosylate. What kind of reaction is occurring? How would you complete the synthesis?When cis-2-decalone is dissolved in ether containing a trace of HCl, an equilibrium is established with trans-2-decalone. The latter ketone predominates in the equilibrium mixture. Propose a mechanism for this isomerization and account for the fact that the trans isomer predominates at equilibrium.What is the major organic product obtained in the following reaction? А | В II D IV CH3 SO3 H2SO4 CH2SO3H SO3H CH3 SO3H SO3H NO2 CH3 II II IV
- s the major organic product obtained from the following reaction? 3 4 2 ○ 1 H₂NNH₂ NH 1 NNH2 3 NH2 2 NHNH22. What organometallic and carbonyl compound could be used to prepare the following compounds? Propose two different carbonyl starting materials and corresponding organometallic reagents for each compound. HO OH4. Give the starting alkene and any other reagents needed to selectively make the following compounds (with no organic byproducts!): OH L Eto OH all OH Br Br Br
- My C mentProblemID=192850292 A&P II Mast o ethyl butanoate ▼ PSY Connect Part A Pears Bb 1574 b Ansv G great H₂C NN Course Home pt My [ chem in career H 12D EXP CONT Predict the major organic product formed when the compound shown below undergoes a reaction with LiAlH4. Interactive 3D display mode CH3 Chen Chen Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Ter * I ο phys G phys N ODevise a synthesis of (E)-tetradec-11-enal, a sex pheromone of the spruce budworm, a pest that destroys fir and spruce forests, from acetylene, Br(CH2)10OH, and any needed organic compounds or inorganic reagents.Give the major product of the reaction shown below. ? Cl₂ H₂O I CI IV Compound I O Compound IV Compound II Compound V Compound III OH LOH do you g V OH LOH