4. In the water and glycerol mixture, the relationship between molar volume and mol fraction of glycerol is given in the following table at 20°C: X₂ (mol fraction of glycerol) 0 0.0212 0.0466 0.1153 0.2269 0.4390 0.6923 1 Molar volume (cm³ mol-¹) 18.05 19.18 20.53 24.18 30.21 41.82 55.87 73.02 (a) Calculate the partial molar volume of water and glycerol as a function of X2. (b) Show that the molar volume in the table can be calculated using the partial molar volume.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.7QAP
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4. In the water and glycerol mixture, the relationship between molar volume and mol
fraction of glycerol is given in the following table at 20°C:
X₂ (mol fraction of glycerol)
0
Molar volume (cm³ mol-¹)
18.05
19.18
20.53
24.18
0.0212
0.0466
0.1153
0.2269
0.4390
55.87
0.6923
1
73.02
(a) Calculate the partial molar volume of water and glycerol as a function of X2.
(b) Show that the molar volume in the table can be calculated using the partial molar
volume.
30.21
41.82
Transcribed Image Text:4. In the water and glycerol mixture, the relationship between molar volume and mol fraction of glycerol is given in the following table at 20°C: X₂ (mol fraction of glycerol) 0 Molar volume (cm³ mol-¹) 18.05 19.18 20.53 24.18 0.0212 0.0466 0.1153 0.2269 0.4390 55.87 0.6923 1 73.02 (a) Calculate the partial molar volume of water and glycerol as a function of X2. (b) Show that the molar volume in the table can be calculated using the partial molar volume. 30.21 41.82
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