3.48. Calculate Z and V for boron trichloride at 300 K and 1.5 bar by the following equations: (a) The truncated virial equation [Eq. (3.38)] with the following values of virial coefficients: B = −724 cm³.mol-1 C= -93,866 cm6.mol-2 (b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized Pitzer correlation [Eqs. (3.58)-(3.62)]

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question
PV
RT
Z=-
=
B C
1+ +
V
V²
PV
Z= =1+
RT
B=
BP c
RTC
BO=0.083
(3.58)
0.422
T1.6
r
BP
RT
B=B⁰+wB¹ (3.59)
(3.61) B¹ = 0.139 -
0.172
T4.2
r
(3.38)
(3.36)
(3.62)
Transcribed Image Text:PV RT Z=- = B C 1+ + V V² PV Z= =1+ RT B= BP c RTC BO=0.083 (3.58) 0.422 T1.6 r BP RT B=B⁰+wB¹ (3.59) (3.61) B¹ = 0.139 - 0.172 T4.2 r (3.38) (3.36) (3.62)
3.48. Calculate Z and V for boron trichloride at 300 K and 1.5 bar by the following
equations:
(a) The truncated virial equation [Eq. (3.38)] with the following values of virial
coefficients:
B = -724 cm³.mol-1 C= -93,866 cm6.mol-2
(b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized
Pitzer correlation [Eqs. (3.58)-(3.62)]
Transcribed Image Text:3.48. Calculate Z and V for boron trichloride at 300 K and 1.5 bar by the following equations: (a) The truncated virial equation [Eq. (3.38)] with the following values of virial coefficients: B = -724 cm³.mol-1 C= -93,866 cm6.mol-2 (b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized Pitzer correlation [Eqs. (3.58)-(3.62)]
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