3.HO4.H₂OH+ (cat.)MeOHNaOMe5.(CH3)2NHTsOH (cat.)

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Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter15: Solutions

Section: Chapter Questions

Problem 3QAP

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On Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado. The spill was neutralized with sodium carbonate: 2HNO3(aq)+Na2CO3(aq)2NaNO3(aq)+H2O(l)+CO2(g) a. Calculate H for this reaction. Approximately 2.0 104 gal nitric acid was spilled. Assume that the acid was an aqueous solution containing 70.0% HNO3 by mass with a density of 1.42 glcm3. What mass of sodium carbonate was required for complete neutralization of the spill, and what quantity of heat was evolved? (Hf for NaNO3(aq) = 467 kJ/mol) b. According to The Denver Post for April 4, 1983, authorities feared that dangerous air pollution might occur during the neutralization. Considering the magnitude of H, what was their major concern?
Lead poisoning has been a hazard for centuries. Some scholars believe that the decline of the Roman Empire can be traced, in part, to high levels of lead in water from containers and pipes, and from wine that was stored in leadglazed containers. If we presume that the typical Roman water supply was saturated with lead carbonate, PbCO3 (Ksp = 7.4 1014), how much lead will a Roman ingest in a year if he or she drinks 1 L/day from the container?
ssume a highly magnified view of a solution of HCI that allows you to “see” the HCl. Draw this magnified view. If you dropped in a piece of magnesium, the magnesium would disappear, and hydrogen gas would he released. Represent this change using symbols for the elements, and write the balanced equation.
Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?
4-20 Calcium oxide is prepared by heating limestone (calcium carbonate, CaCO3) to a high temperature, at which point it decomposes to calcium oxide and carbon dioxide. Write a balanced equation for this preparation of calcium oxide.
Ten mL of concentrated H3PO4 (91.7% by mass, d=1.69g/mL) was accidentally poured into a beaker containing 20.0 g of NaOH. Not all the NaOH was consumed. How many grams of NaOH were left unreacted? The equation for the reaction is H3PO4(aq)+3OH(aq)3H2O+PO43(aq)
A 0.20 mol sample of magnesium burns in air to form 0.20 mol of solid MgO. What amount (moles) of oxygen (O2) is required for a complete reaction?
10A Complete the figure below. Br NaCN DMSO B A NH₂ C 1. Br₂, NaOH 2. H₂O/H* TT. H₂SO4
5. H3CO OH 2 HCONH,
2. Write the complete chemical equation for the neutralization of NaOH with HCI. Include states of matter. (2pts) NaOH + HCl +> H,0 t Na cl i.
Atoms in Element 1 Atoms in Element 2 Atoms in Element 3 Atoms in Element 4 Total Atoms in Molecule Total Elements in Molecule Molecule 2 2H20 4 3CO2 3 6. 9H3PO4 27 36 72 0. 6. 1 20 4 12 20 3. 5Bas(PO4)2 15 10 40 40 105 4 2(NH2S 16 22 4Fes(SOaa 12 12 36 60 3AI(HCO.)a 3 9. 27 48 12 6. 24 42 4 10M9SO. 10 10 40 60 5NaPO. 15 5 20 60 3 7M93(PO4)2 21 14 56 91 8(NH.)PO. 24 96 8 32 160 4 4NaHCO, 4 4 12 9KCIO, 9. 9. 27 45 3 2Ca(CIO.)2 2 4 12 18 3 12Ca (PO4)2 11Ca(NO3)2 7AI(OH). 24
12 AA EE AaBbCcD AaBbCcD AaBbCc AaBbCcf A x' Aa T Normal T No Spac... Heading 1 Heading 2 Paragraph Styl 3 1. 4. B. Fill in the missing reactant or reagent or product to bring about the following chemical reactions. CH, CH, HC 1. CH NaH OH H.C CH;CH21 2. CH, H,O CH, H,SO, H;C Na SH CH,CH,CH,SH CH, CH, H.C CH, CH, pines) 3. 4. 5.

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3. HO 4. H₂O H+ (cat.) MeOH NaOMe 5. (CH3)2NH TsOH (cat.)