3. Consider the following two bimolecular reactions at 700 K: H + 1₂ → HI+I D+ 1₂ → DI + I Neglecting the quantum mechanical zero-point-energy of the reactant and the transition-state, predict the ratio of the rate constants k(H+1₂)/ k(D+1₂).

3. Consider the following two bimolecular reactions at 700 K: H + 1₂ → HI+I D+ 1₂ → DI + I Neglecting the quantum mechanical zero-point-energy of the reactant and the transition-state, predict the ratio of the rate constants k(H+1₂)/ k(D+1₂).

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter13: Chemical Kinetics

Section: Chapter Questions

Problem 13.68QE

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Question

3. Consider the following two bimolecular reactions at 700 K:
H + 1₂ → HI + I
D+ 1₂ → DI + I
Neglecting the quantum mechanical zero-point-energy of the reactant and the transition-state, predict the ratio of
the rate constants k(H+1₂)/k(D+1₂).

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