Determine the rate law 2cl02(aq) + 20Hag→ cl03(ag) + Cl0= (aq)+ H20(1)Experiment[CIO2-], M[ОН-], МInitial Rate (M/s)10.0500.0400.0250.0300.0400.002830.0301.0000.0083

The rate law is defined as the product of concentration of reactant which are raised by respective…

Answered: 2cl02(aq) + 20Haq cloz(aq) + Cl02 (aq)…

2cl02(aq) + 20Haq cloz(aq) + Cl02 (aq) + H20(1) Experiment [CIO2-], M [ОН-1, М Initial Rate (M/s) 0.050 0.040 0.025 2 0.030 0.040 0.0028 3 0.030 1.000 0.0083

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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1. A → B +B (rate constant = k1) 2. A +B → C+D (rate constant = k2 3. D → E+F (rate constant = k3) 4. F+A → D + G (rate constant = k Express the net change of [F] and [G]& (select 2 answers) а. d[F] = -k3[D]+k4[A][F] dt b. d[G] = -k4[A][F] dt d[E] = -k3[D] dt d[F] = k3[D]-k4[A][F] С. dt d. d[F] = k3[E][F]-k4[A][F] dt = k4[A][F] dt е. d[E] = k3[D] dt f. d[G] = k4[D][G] %3D dt d[E] = k3[E][F] dt
2. Consider the kinetic data of the reaction of P + 2 Q + 2+ - PQ, + Z*and answer the succeeding questions: Experiment P (M) Q (M) Temp ("C) Initial Rate, M/s 1 0.01150 0.01200 0.00000 25 4.80 x 10-4 2 0.02300 0.01200 0.00000 25 1.92 x 10-3 3 0.01150 0.02400 0.00000 25 9.60 x 10-4 4 0.04600 0.01200 0.00000 25 7.68 x 10-3 5 0.01150 0.04800 0.00000 25 1.92 x 10-3 6 0.01150 0.01200 0.00000 10 5.10 x 10-5 0.01150 0.01200 0.00000 40 4.55 x 10-3 0.01150 0.01200 0.00500 10 4.98 x 10-5 0.01150 0.01200 0.01050 25 4.82 x 104 10 0.01150 0.01200 0.02100 40 4.44 x 10-3 A. Determine the rate order with respect to P. Determine the rate order with respect to Q. C. Determine the rate law of the reaction. What is the average rate constant? Indicate the appropriate units. E. What is the energy of activation and frequency factor of the reaction without the additive ion? Include the equation of the best fit line of the Arrhenius equation and RSQ Note: Use the calculated rate constant in set up 1 for 25°C…
The following data was collected for the reaction between ethoxide and methyl iodide T(°C) Rate (1/s) T (K) 1/T (1/K) In (rate) 168 273.15 0.00366 5.12 6 354 279.15 0.00358 5.87 12 735 285.15 0.00351 6.60 18 1463 291.15 0.00343 7.29 24 3010 297.15 0.00337 8.01 30 6250 303.15 0.00330 8.74 A plot of In (rate) vs. 1/T using the above table was made and is shown below, and a linear regression line fitted to the data. Using the provided graph, estimate the activation energy (kJ/mol) of the reaction between ethoxide and methyl iodide. Enter your number using 2 decimal places without unit. Gas constant is R = 8.3144598 J. mol 1. K-1. In(k) vs 1/T 9.30 8.80 8.30 7.80 y = -9930.5x + 41.445 R² = 0.9992 2 7.30 6.80 6.30 5.80 5.30 4.80 0.00325 0.00330 0.00335 0.00340 0.00345 0.00350 0.00355 0.00360 0.00365 0.00370 1/T (1/K) Ln(k)
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