2(14)-20+2 king! b) C14H2002 C=0 2. y Carbongl! C-o CH- CH-CH CH, C CH -CH OF CHs S IH CH- CH-CHe 6H 1H so CH3 CH CH 1H 3H 27 se CH pentet 8. octet CH3 CH3 3 PPM CH CH3 -CH ester alkane C=0 C-0 180 160 140 120 100 80 PPM 60 40 20 11 165.9 138.2 135.2 129.9 127.1 21.6

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Is my structure correct based on the c nmr and h nmr ?
Characteristic Values of Chemical Shifts for 'H NMR
Protons bonded to carbon
alkanes:
8 0.9 - 1.7
alkyl halides:
8 2.0-4.0
-CH,
- 0 0.9
benzylic groups:
-CH
-ô 1.3
8 22-3.0
amines:
- ô 1.4
8 24 - 3.6
allylic groups
-c-c-H
ô 1.8 - 2.8
alcohols, ethers, esters:
8 33- 4.5
alkynes:
ô 2.2 - 3.1
EC-H
alkenes:
C=C
8 4.0 - 7.6
LG
carbonyl groups:
ô 1.9 - 3.0
arenes:
à 6.1- 8.4
- ô 2.1
aldehydes:
-C-H
à 9.0 - 10.2
nitriles:
ô 2-3
Protons bonded to heteroatoms (vary with concentration)
R-N-H
Ar-N-H
8 3.0 - 5.0
amines:
ô 1.0 - 3.0
aryl amines:
amides:
8 5.0 - 10.0
alcohols:
R-0-H
ô 2.1 – 5.0
ô 9.8 - 13.0
phenols:
ô 4.0 - 7.5
carboxylic acids:
Ar-0-H
-ċ-0-H
11
Transcribed Image Text:Characteristic Values of Chemical Shifts for 'H NMR Protons bonded to carbon alkanes: 8 0.9 - 1.7 alkyl halides: 8 2.0-4.0 -CH, - 0 0.9 benzylic groups: -CH -ô 1.3 8 22-3.0 amines: - ô 1.4 8 24 - 3.6 allylic groups -c-c-H ô 1.8 - 2.8 alcohols, ethers, esters: 8 33- 4.5 alkynes: ô 2.2 - 3.1 EC-H alkenes: C=C 8 4.0 - 7.6 LG carbonyl groups: ô 1.9 - 3.0 arenes: à 6.1- 8.4 - ô 2.1 aldehydes: -C-H à 9.0 - 10.2 nitriles: ô 2-3 Protons bonded to heteroatoms (vary with concentration) R-N-H Ar-N-H 8 3.0 - 5.0 amines: ô 1.0 - 3.0 aryl amines: amides: 8 5.0 - 10.0 alcohols: R-0-H ô 2.1 – 5.0 ô 9.8 - 13.0 phenols: ô 4.0 - 7.5 carboxylic acids: Ar-0-H -ċ-0-H 11
2(14)-20+2
Ring!
b) C14H2002
C=0
2.
y Carbongl!
C-o
CH- CH-CH
CH, C
CH
OF
CHs
2H
CHe- CH-CH2
CH-COH
CH
6H
1H
CHCH
1H
3H
pentet
27
octet
CH3 3
PPM
CH3
6.
CH3
-CH
CHs
CH3
ト
H.
ester
C=0
C-o
180
160
140
120
100
80
PPM
60
40
20
11
165.9
138.2
135.2
129.9
127.1
エ
82.1
9'IZ
Transcribed Image Text:2(14)-20+2 Ring! b) C14H2002 C=0 2. y Carbongl! C-o CH- CH-CH CH, C CH OF CHs 2H CHe- CH-CH2 CH-COH CH 6H 1H CHCH 1H 3H pentet 27 octet CH3 3 PPM CH3 6. CH3 -CH CHs CH3 ト H. ester C=0 C-o 180 160 140 120 100 80 PPM 60 40 20 11 165.9 138.2 135.2 129.9 127.1 エ 82.1 9'IZ
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